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活性炭吸附法脱除地热水中微量苯酚的试验研究

Study on activated carbon adsorption to remove trace phenol from geothermal water

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【作者】 徐泽王启山鲁金凤肖辉玉

【Author】 XU Ze;WANG Qishan;LU Jinfeng;XIAO Huiyu;College of Environmental Science and Engineering,Nankai University;Key Laboratory of Pollution Processes and Environmental Criteria,Ministry of Education,Nankai University;North China Municipal Engineering Design and Research Institute;

【机构】 南开大学环境科学与工程学院南开大学环境污染过程与基准教育部重点实验室中国市政工程华北设计研究总院

【摘要】 研究了精制椰壳活性炭吸附地热水中微量苯酚的各项参数,通过静态试验系统考察了活性炭用量,水样pH,反应时间,苯酚初始浓度等重要因素,确定了处理地热水中苯酚的最佳条件:活性炭用量6 g/L,pH值6.5,反应时间6 h,苯酚的初始浓度0.5 mg/L,处理效果最佳;并据此进行了动态小试试验,从动力学角度分析吸附原理,其动力学更好的符合伪二级反应动力学模型。将动态试验数据在origin软件中处理,得到适用于活性炭固定床吸附苯酚的穿透曲线模型,旨在为苯酚吸附过程的设计提供参考。

【Abstract】 The treatment of geothermal water containing trace phenol with refined coconut shell activated carbon was studied in this paper.The important factors such as dosage of activated carbon,pH value,adsorption time and initial concentration of phenol have been systematically examined through the static experiment,and the optimum condition of adsorption was determined as follows:dosage of activated carbon was 6g/L,optimum pH was 6.5,adsorption time was 6 h,initial concentration of phenol was 0.5mg/L;according to these factors,the dynamic experiment was done.Study on the adsorption fundamentals from the aspects of kinetics,the adsorption kinetics showed better agreement with pseudo-second-order kinetic model.In order to get the adsorption breakthrough curve model of phenol on activated carbon fixed bed,the experimental data of dynamic experiment was dealt with origin software,and this model is useful for the process design of phenol’ adsorption.

【关键词】 活性炭吸附地热水微量苯酚
【Key words】 activated carbonadsorptiongeothermal watertrace phenol
【基金】 国家自然科学基金项目(51008162);天津市应用基础及前沿技术研究计划资助项目(10JCYBJC03500)
  • 【文献出处】 水资源与水工程学报 ,Journal of Water Resources and Water Engineering , 编辑部邮箱 ,2014年04期
  • 【分类号】X52
  • 【被引频次】3
  • 【下载频次】129
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