【摘要】 通过水热法合成了2个配位聚合物[Mn(cbba)2(bimb)]n(1)和[Cd(cbba)2(mbix)]2n(2)(Hcbba=2-(4′-氯-苯甲酰基)苯甲酸,bimb=1,4-双(咪唑基-1-基)丁烷,mbix=1,3-双(咪唑基-1-基)苯)。并对其进行了元素分析、红外光谱、热重和X-射线单晶衍射测定。这两个配合物通过氢键或π-π相互作用形成了三维超分子网状结构。此外,还研究了配合物1的紫外光谱和配合物2的荧光性质。更多还原

【Abstract】 Two coordination polymers [Mn(cbba)2(bimb)]n(1) and [Cd(cbba)2(mbix)]2n(2)(Hcbba=2-(4′-chlorinebenzoyl)-benzoic acid, bimb=1,4-bis(imidazol-1-yl)-butane, mbix=1,3-bis(imidazol-1-ylmethyl)-benzene) have been hydrothermally synthesized and structurally characterized by elemental analysis, IR spectrum, TG and singlecrystal X-ray diffraction. They are further extended into a three-dimensional supramolecular network structure through hydrogen-bonding or π-π interactions. Moreover, the UV spectrum of complex 1 and luminescent property of complex 2 have been investigated in the solid state. CCDC: 936604, 1; 928554, 2.更多还原