【摘要】 利用2-羟基萘醛、三乙撑四胺与ZnSO4·7H2O或NiCl2·6H2O的溶剂热反应,合成了三个新的Schiff碱的配合物,即[ZnII(L1)(H2O)](1)(H2L1=N,N’-二-(2-羟基萘甲叉基)乙二胺)、[NiII(L2)]Cl·H2O(2)(HL2=9-(9-萘甲叉基,3,6,9-三氮杂壬基)-3,4;7,8-二-(1,2-萘并)-2,6-二氧,9-氮-二环[3,3,1]-3,7-庚二烷)和[NiII2(L3)(Cl)2](3)(H2L3=N,N′-二-[(2-羟基萘甲叉胺)乙基]吡嗪).晶体结构分析揭示:这些配合物中的Schiff碱配体都经历了由金属离子主导的重构,从而例证了金属离子的模板作用.此外,荧光分析表明:1具有光致发光的性质.更多还原

【Abstract】 Solvothermal reactions of 2-formylnaphthol and triethylenetetraamine with ZnSO4·7H2O and NiCl2·6H2O afforded three new Schiff base complexes, namely [ZnII(L1)((H2O)](1)(where H2L1 = N,N’-bis(2-hydroxynaphthal) ethylenediamine), [NiII(L2)] Cl·H2O(2)(HL2 = 9-(9-naphthal,6,9-triazanonyl)-3,4:7,8-bis(2,3-dihydro-1H-naphtho[1,2-e]-2,6-dioxa-bicyclo[3,2,1]nonane and [NiII2(L3)(Cl)2](3)(H2L3 = N,N’-bis- [(2-hydroxynaphthal) ethyl] piperazine). Crystal structural analysis reveals that the ligands in these complexes are formed via metal-governed reconstructions thereby exemplify a "template" effect of metal ion. Besides, the luminescence measurement proves the photoemission of 1.更多还原