【摘要】 用含氮配体Mdcp和柔性的二元羧酸戊二酸为混合配体合成了一个新型的镉配合物[Cd(Mdcp)(GTC)]n(1),并且通过元素分析、热失重分析、红外和X-射线单晶衍射对配合物(1)进行了表征,结构表明此配合物为新颖的二维层状结构,并且通过氢键作用形成三维的网状结构,热失重曲线清晰的表明了各个温度区间内的失重情况.此外研究了配合物(1)的荧光发光性质.更多还原

【Abstract】 A novel metal-organic coordination compound [Cd(Mdcp)(GTC) ]n(1) [Mdcp = 2-(3-methoxyphenyl)-1H-imidazo[4,5-f][1,10]phenanthroline,GTC = pentanedioic acid] has been synthesized by hydrothermal reactions and characterized by elemental analysis,thermogravimetric(TG) analysis,infrared spectrum(IR) and single-crystal X-ray diffraction.The single-crystal X-ray diffraction result reveals that the compound(1) exhibits two-dimensional(2D) layer architecture which is linking to 3D structure by the H-bond intersections.The TG analysis result shows the courses of weight loss.We also study the luminescent properties of the compound(1).更多还原