【摘要】 采用温和的溶液法制备了五个掺杂过渡金属离子的含钕多酸化合物(TM=Mn(1),Co(2),Ni(3),Cu(4),Zn(5)),通过X-射线粉末衍射确定了这些化合物的晶相,并通过电感耦合等离子发射光谱、固体紫外-可见漫反射光谱等表征确定了过渡金属离子的掺杂。探讨了掺杂过渡金属离子对该系列化合物多色性质、光致发光性质、以及磁性质的影响。研究发现,过渡金属离子的掺杂对含钕多酸化合物有明显的着色效果,并且丰富了该系列化合物的多色性。更多还原

【Abstract】 Five Nd-contained POM complexes doped with transition metal were synthesized by adopting mild aqueous method( TM = Mn( 1),Co( 2),Ni( 3),Cu( 4),Zn( 5)). The structures of complexes were characterized by X-ray powder diffraction,and the presence of transition metal was confirmed by inductively coupled plasma optical emission spectrometry and solid-state UV-Vis diffraction spectrometry. The influence of transition metal dopant on multi-color properties,fluorescence,and magnetism were discussed as well. It was found that the complexes with dopant showed distinct tinctorial effect,and various multi-color effect.更多还原