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蒙脱石对水中Ni2+的吸附模型研究

Research on the Adsorption Model of Nickel Ions on Montmorillonite

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【作者】 王洪丽; 杨斌; 郭玲;

【Author】 WANG Hong-li;YANG Bin;GUO Ling;Yutian County Environmental Protection Bureau;

【机构】 玉田县环境保护局;

【摘要】 吸附法是一种常用于去除废水中重金属离子的方法。近年来,对新型吸附剂的探索已成为研究的热点。蒙脱石是一种2:1型的粘土矿物,具有较高的比表面积和较强的吸附能力。本文采用拟实验方法,研究了蒙脱石在常温(293 K)对水溶液中Ni2+的吸附特性,考察了初始浓度对吸附效果的影响。结果表明,蒙脱石对Ni2+的吸附等温线可用Langmuir吸附等温方程、Freundlich吸附等温模型和Dubinin-Radushkevich(D-R)等温吸附模型进行描述,其中Langmuir吸附等温方程的拟合效果较佳(R2=0.999)。在293 K时,最大饱和吸附容量为153.85 mg/g,表明蒙脱石对Ni2+的吸附类型是物理吸附。

【Abstract】 Adsorption method is one of the most common methods to remove heavy metals from wastewater. In recent years, research on new adsorbents has become a hot spot. Montmorillonite(MMT), a 2:1 type of clay mineral has high surface area and high adsorption capacity. In this paper, adsorption of Ni2+ from aqueous solution on MMT was studied at 293 K by using batch equilibrium approach. The adsorption conditions were studied, too. The results show that Ni2+ adsorption isotherm on MMT can be described by Langmuir adsorption isotherm model, Freundlich isotherm model and Dubinin-Radushkevich(D-R) isotherm model. The fitting result of Langmuir adsorption isotherm model is the best(R2=0.999). The maximum adsorption capacity is 153.85mg/g at 293 K, which proves that the adsorption process belongs to physical adsorption process.

【关键词】 蒙脱石; 吸附; 镍离子;
【Key words】 montmorillonite; adsorption; nickel ions;
  • 【文献出处】 辽宁化工 ,Liaoning Chemical Industry , 编辑部邮箱 ,2014年10期
  • 【分类号】X703.1
  • 【被引频次】3
  • 【下载频次】114
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