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不同Al含量Cu-Al合金内氧化后的组织对比

Comparative analysis of internal oxidation microstructure of Cu-Al alloy with different Al content

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【作者】 李玉娟任凤章王晓伟李炎魏世忠

【Author】 LI Yu-juan;REN Feng-zhang;WANG Xiao-wei;LI Yan;WEI Shi-zhong;School of Materials Science and Engineering,Henan University of Science and Technology;Technology Research Institute,China Aviation Optical-Electrical Technology Co Ltd;

【机构】 河南科技大学材料科学与工程学院中航光电科技股份有限公司连接技术研究院

【摘要】 不同Al含量(0.16%、0.3%和0.5%)的Cu-Al合金薄板使用Cu2O粉末包埋法内氧化,制备Cu-Al2O3弥散强化铜合金,并对其微观组织进行分析。结果表明,合金的内氧化层表层晶粒均比内部晶粒明显细小,表面晶粒为5~30μm,内部晶粒为30~100μm;随内氧化时间增加,内氧化层深增加,但随Al含量增加而减小;内氧化层的微观组织为大量细小γ-Al2O3相弥散分布在铜基体上;内氧化层表层γ-Al2O3粒子大小为20~50 nm,间距为50~150 nm,γ-Al2O3粒子与基体Cu的界面匹配关系是(022)Cu//(220)γ,为共格界面。

【Abstract】 Internal oxidation of Cu-Al alloy with different Al content( 0. 16% 、0. 3% and 0. 5%) was carried out in Cu2 O powder oxidizer. The microstructure of Cu-Al2O3 composites was investigated by metallurgical microscope and transmission electron microscope( TEM). The results show that after internal oxidation,the grains of surface layer of the alloy are smaller than that of inside layer. The surface grain size is 5-30 μm,while the inside grain size is 30-100 μm. Internal oxidation depth of the alloy increases gradually with increasing of oxidation time,but decreases with increasing of Al content. Lots of small γ-Al2O3 particles with diameter size of about 20-50 nm and particle spacing of 50-150 nm distribute dispersedly in Cu matrix. The two phases between γ-Al2O3 and Cu matrix have a semicoherent relationship of( 022)Cu/ /( 220)γ.

【基金】 国家自然科学基金项目(51201061);长江学者和创新团队发展计划项目(IRT1234);河南省科技创新人才计划(144200510001);河南省重点攻关项目(092102210012)
  • 【文献出处】 材料热处理学报 ,Transactions of Materials and Heat Treatment , 编辑部邮箱 ,2014年09期
  • 【分类号】TB333
  • 【被引频次】5
  • 【下载频次】203
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