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第二松花江流域水体表层沉积物多环芳烃的污染特征与暴露风险评价

Pollution Characteristics and Exposure Risk Assessment of Polycyclic Aromatic Hydrocarbons (PAHs) in the Surface Sediments of Second Songhua River Basin

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【作者】 刘宝林董德明花修艺李明

【Author】 LIU Bao-lin;DONG De-ming;HUA Xiu-yi;LI Ming;College of Environment and Resources,Jilin University;College of Chemistry,Changchun Normal University;

【机构】 吉林大学环境与资源学院长春师范大学化学学院

【摘要】 考察第二松花江表层沉积物中16种多环芳烃类化合物(PAHs)的质量比.结果表明:16种PAHs的总质量比为350.0~3 877.4ng/g,平均质量比为1 322.6ng/g,4~6环相对丰度为58.5%,2~3环相对丰度为41.5%;PAHs在上游水区的质量比最高,与长江河口相近;除河源区外,大部分水域沉积物中PAHs人为来源为化石燃料的燃烧,少部分为石油源;除表层沉积物中芴和苊烯可能具有一定的暴露风险外,其他PAHs存在的暴露风险较小,即第二松花江沉积物PAHs总量远低于风险评估低值(ERL),存在的暴露风险较小.

【Abstract】 The mass contents of 16polycyclic aromatic hydrocarbons(PAHs)in the surface sediments of the second Songhua River were investigated.The total PAHs mass rate varied from 350.0to3 877.4ng/g,with the mean value being 1 322.6ng/g.The 4—6rings PAHs made up 58.5%,whereas 2—3rings PAHs made up 41.5%.The study shows that the mass content of PAHs was the highest in the surface sediments of the upstream of the second Songhua River.The total mass content of PAHs was close to that of the Yangtze River estuary.In addition to that from the source regions,the PAHs in the sediments were mainly from anthropogenic emission.Anthropogenically produced PAHs in the sediments in most of waters was from the burning of fossil fuels and a small part was from the petroleum derived.Exposure risk assessment results show that in addition to the fluorene and acenaphthylene,there was not obvious risk of exposure of other polycyclic aromatic hydrocarbons.The total mass content of PAHs in the sediments of the second Songhua River was much lower than the effects range-low(ERL),and there was not obvious risk of exposure basically.

【基金】 国家自然科学基金(批准号:31200407);国家“水体污染控制与治理”科技重大专项基金(批准号:2009ZX07207-001-03);高等学校博士学科点专项基金(批准号:20100061110041);长春师范学院自然科学基金(批准号:长师院自科合字[2010]第037号)
  • 【文献出处】 吉林大学学报(理学版) ,Journal of Jilin University(Science Edition) , 编辑部邮箱 ,2014年01期
  • 【分类号】X820.4
  • 【被引频次】14
  • 【下载频次】176
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