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连续铸造Cu-Cr-Zr合金的时效动力学分析

Aging Kinetics Analysis of Cu-Cr-Zr Alloy Prepared by Continuous Casting

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【作者】 王松庄滇湘谢明张吉明陈敬超柳青周晓龙

【Author】 WANG Song;ZHUANG Dian-xiang;XIE Ming;ZHANG Ji-ming;CHEN Jing-chao;LIU Qing;ZHOU Xiao-long;State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals,Kunming Institute of Precious Metals;College of Materials Science and Engineering,Kunming University of Science and Technology;

【机构】 昆明贵金属研究所稀贵金属综合利用新技术国家重点实验室昆明理工大学材料科学与工程学院

【摘要】 对经过连续铸造、固溶和冷拉拔的Cu-0.85Cr-0.15Zr合金进行时效处理,研究了时效处理工艺对该合金性能的影响,并对该合金的时效动力学进行了分析。结果表明:Cu-0.85Cr-0.15Zr合金经450℃/3 h时效处理后可以获得较好的综合性能,合金的显微硬度与导电率分别达到237 HV和70.5%IACS。采用相变动力学Avrami经验方程来描述Cu-Cr-Zr合金的时效过程,得到450℃时效时合金的时效动力学方程为f=1-exp(-0.0063t0.802 5),并作出了合金时效时的等温转变动力学"S"曲线。

【Abstract】 Effects of aging treatment on microstructures and properties of the Cu-0.85Cr-0.15Zr alloy produced by continuous casting,solution treatment and cold drawing process are investigated,and the aging kinetics of the alloy is analyzed.Results show that a better combination of properties is obtained after the Cu-0.85Cr-0.15Zr alloy aged at 450 ℃ for 3 h,consequently the micro-hardness and electrical conductivity of the alloy are 237 HV and 70.5%IACS,respectively. The empirical equation of Avrami phase transformation kinetics is applied to describe the aging process of Cu-Cr-Zr alloy,and the aging kinetics equation at 450 ℃ is given as f=1-exp(-0.006 3t0.802 5),through which the isothermal transformation kinetics S curve is drawn.

【基金】 国家自然科学基金项目(51164015、u0837601);国家科技支撑计划项目(2012BAE06B05);昆明市科技创新团队项目(20120101AR070005)
  • 【文献出处】 电工材料 ,Electrical Engineering Materials , 编辑部邮箱 ,2014年02期
  • 【分类号】TG146.11;TG156.92
  • 【被引频次】6
  • 【下载频次】105
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