【摘要】 以吡啶-4-甲醛缩4-氨基安替比林和Cd(NO3)2·4H2O为原料,溶剂热法成功合成出了一个新型Cd(II)配合物[Cd2(L4)4(NO3)4](L4=吡啶-4-甲醛缩4-氨基安替比林),并通过红外光谱、拉曼光谱、元素分析、X-粉末衍射、单晶X射线衍射对配合物的单晶结构进行了表征.该配合物属于单斜晶系,空间群C2/c,晶胞参数a=22.585(9),b=9.636(4),c=18.827(8),α=90°,β=125.152(6)°,γ=90°,V=3350(2)3,Z=2,Dc=1.628Mg/m3,F(000)=1 672,μ=0.722mm-1,R1=0.0488,wR2=0.0967(I>2σ(Ⅰ)).室温固态荧光测试显示,配合物在517nm(λmax)具有强的荧光吸收.更多还原

【Abstract】 A new cadmium(Ⅱ)complex[Cd2(L4)4(NO3)4](L4=pyridine-4-carboxaldehyde and 4-aminoantipy-rine)has been solvothermally synthesized and structurally characterized by elemental analysis,IR,Raman,XRD,and single-crystal X-ray diffraction.The compound belongs to monoclinic system with space group C2/c and cell parameter:a=22.585(9),b=9.636(4),c=18.827(8),α=90°,β=125.152(6)°,γ=90°,V=3350(2)3,Z=2,Dc=1.628Mg/m3,F(000)=1 672,μ=0.722mm-1,R1=0.048 8,wR2=0.0967[I>2σ(Ⅰ)].The cadmium(Ⅱ)complex exhibits strong fluorescence absorption at 464nm(λmax)in the solid state at room temperature.更多还原