【摘要】 本文围绕近年来基于配位聚合物的纳米材料,包括配合物纳米材料和以其为前体制备的各种氧化物、硫化物等半导体材料和磁性材料的可控合成研究工作,总结了配合物纳米材料的制备方法,主要有液相法、微乳法、扩散法、界面反应法、水热/溶剂热法、高温裂解法等,以及应用方面的研究进展,并展望了配合物纳米材料今后可能的发展方向。更多还原

【Abstract】 The progress of the controllable syntheses of the nanomaterials based on the coordination complexes is reviewed. The coordination complexes can be used as solid-state precursors for preparation of metal oxides,metal sulfides,and semiconductors,as well as hybrid carbonous nanomaterials via solid-state decomposition,solvothermal or hydrothermal reaction,mircoemulsion method,diffusion method,interfacial reaction,microwave-assisted process, and so on. From the view of material design,the coordination complexation with different structures and compositions is a simple and rational route to synthesize novel nano-/microstructured materials. Furthermore,the development direction of nanomaterials constructed by complexes is look into the future.更多还原