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非晶态Ni-B/MCM-22催化剂上二氧化碳甲烷化的研究
Methanation of carbon dioxide on the amorphous Ni-B/MCM-22 catalysts
【摘要】 本文采用固定床反应装置考察了非晶态镍基催化剂CO2甲烷化催化反应活性。研究结果表明:以化学还原法制备的非晶态镍基催化剂的二氧化碳甲烷化活性较高;由XRD及TEM结果可知,非晶态镍基催化剂中镍的分散度较高;以MCM-22分子筛为催化剂载体的非晶态镍基催化剂CO2的转化率高于以γ-Al2O3为载体的非晶态催化剂。
【Abstract】 The catalytic performance of methanation of CO2 was investigated on the amorphous nickel-based catalysts in the fixed bed reactor. Research results showed that the conversion of CO2 on amorphous Ni-based catalysts was higher than that on the catalyst prepared by impregnation method. The XRD and TEM results indicated that the high dispersion of nickel existed in the amorphous Ni-based catalysts. The conversion of CO2 on the amorphous Ni-based/MCM-22 catalysts was higher than that on the amorphous Ni-based/γ-Al2O3 catalysts.
【关键词】 MCM-22;
非晶态催化剂;
镍基催化剂;
二氧化碳甲烷化;
【Key words】 MCM-22; amorphous catalyst; Ni-based catalyst; methanation of carbon dioxide;
【Key words】 MCM-22; amorphous catalyst; Ni-based catalyst; methanation of carbon dioxide;
【基金】 黑龙江省教育厅基金资助项目(11551120)
- 【文献出处】 化学工程师 ,Chemical Engineer , 编辑部邮箱 ,2014年08期
- 【分类号】O643.36
- 【被引频次】3
- 【下载频次】121