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电极工艺对甲酸氧化阳极催化活性的影响
Effect of the Electrode Process of Formic Acid Anodic Oxide Catalytic Activity
【摘要】 采用纳米石墨为原料,硼氢化钠作为还原剂制得石墨烯载体GN,并制备钯催化剂Pd/GN.将催化剂均匀的涂抹在碳纸上制备工作电极后,一种采用电极处理Pd/GN-1,另一种不采用任何处理Pd/GN-2.发现采用电极处理制备的石墨烯载Pd催化剂电极对甲酸氧化阳极催化活性和稳定性有很大的提高.
【Abstract】 The graphene GN from Nano graphite is obtained by sodium NaBH4as reducing agent,and with this kind of graphene as a supporter,Pd catalyst was prepared and designed as Pd / GN. By spread evenly prepared a catalyst in the preparation of the working electrode on carbon paper and then one use electrode process of treatment Pd / GN-1,another does not use any treatment Pd / GN-2. Preparation of electrode process treatment palladium catalyst Pd / GN-1 than Pd / GN-2 for formic acid electrooxidation have greatly improved and a good stability.
【基金】 黑龙江省自然科学基金(B201002);哈尔滨市科技创新人才专项资金项目(2010RFXXG018);黑龙江省高校科技创新团队建设计划(2011TD010)
- 【文献出处】 哈尔滨师范大学自然科学学报 ,Natural Science Journal of Harbin Normal University , 编辑部邮箱 ,2014年02期
- 【分类号】TQ150;TM911.4
- 【下载频次】35