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改性沸石对废水中Cu2+、Cr3+的去除作用研究
Research on the removing effect of modified clinoptilolite on Cu2+ and Cr3+ from wastewater
【摘要】 用Na OH碱熔-水热法处理得到的改性斜发沸石作为吸附交换剂,对模拟废水中以Cu2+、Cr3+为代表的重金属离子进行吸附处理。研究了不同吸附时间、投加量以及初始浓度条件下,改性斜发沸石对Cu2+、Cr3+的去除效果。实验结果表明:改性沸石与水样中Cu2+、Cr3+的质量比分别为18.75∶1、13.33∶1时,对Cu2+、Cr3+的去除率分别达88.0%、87.4%,且为快速吸附平衡过程。此外,用Na Cl溶液和Na Cl溶液加氨水对吸附Cu2+饱和的改性沸石进行再生实验,再生率较高,改性斜发沸石可以多次重复利用。
【Abstract】 The modified clinoptilolite,which was obtained by Na OH alkali fusion-hydrothermal treatment process,has been used as an adsorption exchanger. Adsorption treatment of heavy metal ions, represented by Cu2+,and Cr3+in simulated wastewater is conducted. Under different conditions,such as adsorption time, dosages and initial concentration,the removing effects of modified clinoptilolite on Cu2 +and Cr3 +from water samples are studied. The experimental results show that the mass ratio of modified clinoptilolite and Cu2+,Cr3+in water samples is 18.75∶1 and13.33 ∶1,respectively,the Cu2 +and Cr3 +removing rates are 88.0% and 87.4%,respectively. It is a rapid adsorption equilibrium process. In addition,the regeneration experiment on modified chinoptilolite,which was saturated with Cu2+by sodium chloride solution and sodium chloride solution+ammonia,has been accomplished. The regenerating rate is pretty high and modified clinoptilolite can be used repeatedly many times.
- 【文献出处】 工业水处理 ,Industrial Water Treatment , 编辑部邮箱 ,2014年12期
- 【分类号】X703
- 【被引频次】5
- 【下载频次】203