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改性沸石对废水中Cu2+、Cr3+的去除作用研究

Research on the removing effect of modified clinoptilolite on Cu2+ and Cr3+ from wastewater

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【作者】 张义婕司志华胡晓静石玉坤朱宝林郑晓广黄唯平

【Author】 Zhang Yijie;Si Zhihua;Hu Xiaojing;Shi Yukun;Zhu Baolin;Zheng Xiaoguang;Huang Weiping;College of Chemistry,Nankai University,Tianjin Key Laboratory of Metal & Molecule-based Material Chemistry;Shandong Dongchang Fine Chemical Technology Co.,Ltd.;

【机构】 南开大学化学学院,金属及分子基材料化学天津市重点实验室山东东昌精细化工科技有限公司

【摘要】 用Na OH碱熔-水热法处理得到的改性斜发沸石作为吸附交换剂,对模拟废水中以Cu2+、Cr3+为代表的重金属离子进行吸附处理。研究了不同吸附时间、投加量以及初始浓度条件下,改性斜发沸石对Cu2+、Cr3+的去除效果。实验结果表明:改性沸石与水样中Cu2+、Cr3+的质量比分别为18.75∶1、13.33∶1时,对Cu2+、Cr3+的去除率分别达88.0%、87.4%,且为快速吸附平衡过程。此外,用Na Cl溶液和Na Cl溶液加氨水对吸附Cu2+饱和的改性沸石进行再生实验,再生率较高,改性斜发沸石可以多次重复利用。

【Abstract】 The modified clinoptilolite,which was obtained by Na OH alkali fusion-hydrothermal treatment process,has been used as an adsorption exchanger. Adsorption treatment of heavy metal ions, represented by Cu2+,and Cr3+in simulated wastewater is conducted. Under different conditions,such as adsorption time, dosages and initial concentration,the removing effects of modified clinoptilolite on Cu2 +and Cr3 +from water samples are studied. The experimental results show that the mass ratio of modified clinoptilolite and Cu2+,Cr3+in water samples is 18.75∶1 and13.33 ∶1,respectively,the Cu2 +and Cr3 +removing rates are 88.0% and 87.4%,respectively. It is a rapid adsorption equilibrium process. In addition,the regeneration experiment on modified chinoptilolite,which was saturated with Cu2+by sodium chloride solution and sodium chloride solution+ammonia,has been accomplished. The regenerating rate is pretty high and modified clinoptilolite can be used repeatedly many times.

【关键词】 改性沸石重金属离子吸附
【Key words】 modified clinoptiloliteheavy metal ionsadsorption
【基金】 国家自然科学基金项目(21373120,21071086)
  • 【文献出处】 工业水处理 ,Industrial Water Treatment , 编辑部邮箱 ,2014年12期
  • 【分类号】X703
  • 【被引频次】5
  • 【下载频次】203
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