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导电剂对氧化钌基超级电容器电极材料性能的影响

Study on effect of conductive agent on the performances of ruthenium oxide electrode materials

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【作者】 卢云元杰宫岩坤胡永达杨春

【Author】 LU Yun;YUAN Jie;GONG Yan-kun;HU Yong-da;YANG Chun;State Key Laboratory of Electronic Thin Films and Integrated Devices,University of Electronic Science and Technology of China;

【机构】 电子科技大学电子薄膜与集成器件国家重点实验室

【摘要】 采用液相共沉积法合成了RuO2/AC复合电极材料,用扫描电镜对不同导电剂材料的形貌进行表征,进而通过循环伏安法、恒流充放电、交流阻抗谱研究了不同导电剂对RuO2/AC复合电极材料超级电容器性能的影响。结果表明,在38%(质量分数)的H2SO4溶液中,电流密度为2 m A/cm2,以CNTs、AB、KS6、Super PLi为导电剂时比容量和ESR分别为689,556,574和512 F/g,0.19,0.36,0.32和0.41Ω。

【Abstract】 Amorphous hydrous ruthenium oxide/active carbon composite electrode materials prepared by the liquid phase codeposition. The morphology of the conductive agents were investigated by SEM. Based on the cyclic voltammetry,AC impedance spectroscopy and constant current charge-discharge techniques,the performances of the RuO2/AC composite electrodes materials which add different conductive agent are investigated. The results show that when CNTs,AB,KS6 and Super P Li were used as conductive agent,the materials specific capacitance of RuO2/AC composite electrodes was689,556,574 and 512 F/g,respectively,the equivalent series resistance was 0. 19,0. 36,0. 32 and 0. 41 Ω,measured at 5 m V/s in 38%(mass fraction) H2SO4 and under the current density of 2 m A/cm2.

【关键词】 RuO2/AC导电剂ESR比电容
【Key words】 RuO2/ACconductive agentESRspecific capacity
【基金】 “十二五”电子预研基金资助项目(BW040418)
  • 【文献出处】 功能材料 ,Journal of Functional Materials , 编辑部邮箱 ,2014年S2期
  • 【分类号】TM53
  • 【被引频次】4
  • 【下载频次】183
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