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γ辐照聚碳硅烷先驱丝在Ar与NH3气氛中热解及结构演变研究

Chemical structure evolution of polycarbosilane precursor fibers heated in Ar and NH3 atmosphere

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【作者】 黎阳高家诚

【Author】 LI Yang;GAO Jia-cheng;College of Materials Science and Engineering,Chongqing University;School of Materials and Architecture Engineering,Guizhou Normal University;

【机构】 重庆大学材料科学与工程学院贵州师范大学材料与建筑工程学院

【摘要】 研究了γ辐照聚碳硅烷(polycarbosilane,PCS)先驱丝在Ar与NH3中的热解过程,探讨了气氛与温度对化学结构演变、元素组成、晶型结构和微观形貌的影响。结果表明,热解温度低于600℃时,气氛对化学结构无影响;热解温度达700℃时,Ar中先驱丝的化学结构主要由Si—O—Si和Si—CH2—Si构成,而在NH3中发生了N与C的亲核取代反应,化学结构主要由Si—O—Si、Si—NH—Si和Si—NH2构成;1 000℃时,Ar中得到β-SiC晶型的SiC陶瓷纤维,NH3中得到无定型Si3N4陶瓷纤维。

【Abstract】 The pyrolysis process ofγ-ray irradiation curing of polycarbosilane precursor fibers in argon and ammonia atmosphere were studied.The effect of atmosphere and temperature on chemical structure evolution,elemental composition,crystal structure and microstructure were discussed.Results showed that the chemical structures of the fibers treated in two kinds of atmosphere had no difference below 600℃.At the temperature of 700℃,the chemical structures of the fibers treated in argon were composed of Si—O—Si and Si—CH2—Si, while the fibers treated in ammonia composed of Si—O—Si,Si—NH—Si and Si—NH2.When the temperature reached 1 000℃,SiC ceramic fibers withβ-SiC micro crystal were obtained in argon and amorphous Si3N4ceramic fibers in ammonia.

【关键词】 聚碳硅烷先驱丝γ射线ArNH3
【Key words】 polycarbosilane precursor fibersγ-rayargonammonia
【基金】 贵州省自然科学基金资助项目([2010]2008);贵州省教育厅重点实验室资助项目(黔教合KY字[2012]004)
  • 【文献出处】 功能材料 ,Journal of Functional Materials , 编辑部邮箱 ,2014年05期
  • 【分类号】TQ343.6
  • 【被引频次】2
  • 【下载频次】54
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