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添加纳米银粉对导电胶体积电阻率的影响

Effect of Nano-sized Silver Powders on the Volume Resistivity of Conductive Adhesives

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【作者】 樊明娜李世鸿刘继松黄富春

【Author】 FAN Mingna;LI Shihong;LIU Jisong;HUANG Fuchun;State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals,Kunming Institute of Precious Metals;

【机构】 昆明贵金属研究所稀贵金属综合利用新技术国家重点实验室

【摘要】 将3种银粉,即:片状银粉、片状银粉加入5%纳米银粉的混合粉、片状银粉加入10%纳米银粉的混合粉,加入双酚F环氧树脂中配制导电胶。通过在玻璃基片上印刷导电胶条,固化后测量其长、宽、厚和电阻,利用公式ρ=Rs/l计算体积电阻率。结果表明,当纳米银粉添加量为5%时,体积电阻率出现明显下降,混合银粉含量为75%时的体积电阻率能达到1.6×10-4?·cm。在接近"穿流阈值"时,加入纳米银粉可以增大颗粒间的接触面积,形成更多的导电通路,能降低导电胶的体积电阻率。

【Abstract】 Conductive adhesives were made by adding micro-sized silver flakes, mixed-sized silver powders with the addition of 5% nano-sized silver and mixed-sized silver powders with the addition of 10% to the bisphenol F epoxy resin. By printing the conductive tap on glass substrate and caring, the length, width, thickness and resistance were measured. Then the volume resistivity could be calculated by the formula ρ=Rs/l. The results indicated that the addition of nano-sized silver powders to silver flakes usually increases its resistivity, only near the percolation threshold, the addition of nano-sized silver powders decreases the resistivity by helping to form the conductive path. When the increment of nano-silver powders was 5%, the volume resistivity decreased most significantly, the volume resistivity can reach 1.6×10-4 ?·cm with the content of 75%.

【基金】 国家科技支撑项目(2012BAE06B00)
  • 【分类号】TB383.1
  • 【被引频次】20
  • 【下载频次】466
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