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改性粉煤灰填充天然橡胶的性能研究

The Study on Stuffing Properties of Natural Rubber Reinforcing by Fly Ash

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【作者】 许逵陈静彭政潘荣楷马琳

【Author】 XU Kui;CHEN Jing;PENG Zheng;PAN Rong-kai;MA Lin;Agriculture Ministry Key Laboratory of Natural Rubber Processing,Agricultural Products Processing Research Institute,Chinese Academy of Tropical Agricultural Sciences;Chemistry Science and Technology School,Institute of Physical Chemistry Zhanjiang Normal University;

【机构】 中国热带农业科学院农产品加工研究所,农业部热带作物加工重点实验室化学科学与技术学院,物理化学研究所湛江师范学院

【摘要】 通过煅烧温度、偶联剂用量、煅烧时间三个因素来研究粉煤灰的活化改性条件。将活化改性的粉煤灰填充天然橡胶,测定混炼胶的硫化特性和物理机械性能。结果表明,高温热处理有助于提高粉煤灰对天然橡胶的补强。用硅烷偶联剂KH570改性粉煤灰补强橡胶,其拉伸强度显著增加。当炭黑份数≤20%时,随炭黑的比例增加,拉伸强度快速增加,当炭黑份数>20%时,性能增加的幅度降低。当炭黑比例达到50%时,拉伸强度明显低于炭黑,但300%定伸应力值接近纯炭黑补强天然橡胶。

【Abstract】 By changing the activated and modified conditions such as calcining temperature,coupling agent,calcining time on the fly ash to study the best activated and modified conditions.The properties of vulcanization and physical and mechanical were measured.The results show that high temperature calcing can help the reinfrocing properties to natural rubber(NR)but not obviously.Combined the fly ash with different proportions of carbon black(CB),when the quality ratio of carbon black reaches≤20%,tensile strength of NR will increase obviously as the increment of ratio of carbon black.When the quality ratio of carbon black reaches>20%,the improvement rate of property of NR vulcanizes would be dropping.But when the weight ration of CB reached to 50%,300% modulus of NR vulcanizes is close to pure CB reinforced NR.

【关键词】 粉煤灰改性天然橡胶补强性能
【Key words】 Fly ashModificationNatural rubberReinforcing properties
【基金】 农业部热带作物产品加工重点实验室资助项目(KLTCPP201301);海南省自然科学基金资助项目(511118);福建省晋江市科技局资助项目
  • 【文献出处】 高分子通报 ,Polymer Bulletin , 编辑部邮箱 ,2014年01期
  • 【分类号】TQ332
  • 【被引频次】6
  • 【下载频次】136
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