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基于DOPPP的高效白光OLED器件

High efficient white OLEDs based on DOPPP

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【作者】 张刚田晓萃赵丽娜汪津姜文龙董玮利张希艳

【Author】 ZHANG Gang;TIAN Xiao-cui;ZHAO Li-na;WANG Jin;JIANG Wen-long;DONG Wei-li;ZHANG Xi-yan;School of Material Science and Engineering,Changchun University of Science and Technology;Key Laboratory on Functonal Materials Physics and Chemistry of Ministry of Education of China,College of Information Technology,Jilin Normal University;

【机构】 长春理工大学材料科学与工程学院吉林师范大学信息技术学院

【摘要】 采用真空热蒸镀的方法,以荧光染料1-(2,5-dimethoxy-4-(1-pyrenyl)-phenyl)pyrene(DOPPP)为蓝发光层,5,6,11,12-Tetraphenylnaphthacene(Rubrene)为黄发光层,制备了结构为ITO/m-MTDATA(10nm)/NPB(30nm)/Rubrene(0.2nm)/DOPPP(xnm)/TAZ(10nm)/Alq3(30nm)/LiF(0.5nm)/Al的双发光层的高效白色有机电致发光器件(OLED)。通过调整DOPPP层的厚度,研究器件的发光性能。当DOPPP层厚小于25nm时,器件以黄光发射为主;当DOPPP层厚为25nm时器件的性能最佳,在电流密度为209.18mA/cm2时,获得最大亮度为9 232cd/m2,在电流密度为103.712mA/cm2时获得最大电流效率4.68cd/A,并随着驱动电压的升高,器件的色坐标从(0.366,0.365)变化到(0.384,0.399),都在白光的范围之内;当DOPPP层厚度超过25nm时,器件的效率和亮度都开始下降。

【Abstract】 The double-light-emitting-layer white organic electroluminescent devices with the structure of ITO/m-MTDATA(10nm)/NPB(30nm)/Rubrene(0.2nm)/DOPPP(xnm)/TAz(10nm)/Alq3(30nm)/LiF(0.5nm)/Al have been fabricated by using the method of vacuum thermal evaporation.The fluorescent dye 1-(2,5-dimethoxy-4-(1-pyrenyl)-phenyl)pyrene(DOPPP)is the blue emitting layer and the 5,6,11,12-Tetraphenylnaphthacene(Rubrene)is the yellow emitting layer.The luminescence performances of the devices are studied by adjusting the thickness of DOPPP layer.When the thickness of DOPPP layer is less than 25 nm,the device has yellow emission mainly.When the thickness is 25 nm,the performance of the device is the best.The maximum luminance is 9232cd/m2 when the current density is 209.18mA/cm2,and the maximum current efficiency is 4.68cd/A when the current density is103.712mA/cm2.With the increasing of voltage,color coordinates change from(0.366,0.365)to(0.384,0.399).They are in the scope of white light.It is a better white light emission.When the thickness is more than 25 nm,the efficiency and luminance of the devices begin to reduce.

【基金】 国家自然科学基金(50772016);吉林省科技发展(20100510、20101512、201215221);吉林省教育厅“十二五”科学技术研究(2011154,2012175,2012176,2013208)资助项目
  • 【文献出处】 光电子·激光 ,Journal of Optoelectronics.Laser , 编辑部邮箱 ,2014年12期
  • 【分类号】TN312.8
  • 【被引频次】1
  • 【下载频次】192
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