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蓝绿色磷光OLED的制备及发光性能研究

Preparation and photolumiescence properties of the OLED with greenish-blue phosphor

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【作者】 高淑雅陈维铅吕磊刘杰董亚琼张方辉

【Author】 GAO Shu-ya;CHEN Wei-qian;LV Lei;LIU Jie;DONG Ya-qiong;ZHANG Fang-hui;School of Materials Science &Engineering,Shaanxi University of Science &Technology;School of Electrical &Information Engineering,Shaanxi University of Science & Technology;

【机构】 陕西科技大学材料科学与工程学院陕西科技大学电子与工程学院

【摘要】 以mCP为主体发光材料,蓝绿色磷光染料BGIr1作为掺杂剂,制备了6种不同BGIr1掺杂量的蓝绿色磷光有机电致发光器件(OLED),研究了不同掺杂量对蓝绿色磷光OLED器件发光特性的影响。制得器件的结构为ITO/MoO3(20nm)/NPB(40nm)/mCP:BGIr1(x%,30nm)/BCP(10nm)/Alq3(20nm)/LiF/Al(100nm),其中x%为发光层中磷光染料BGIr1的掺杂量(质量分数)。结果表明,BGIr1掺杂量为18%时,获得器件的发光性能最佳。18%BGIr1掺杂器件在488nm和512nm处获得两个主发射峰,当电流密度为26.5mA/cm2时,获得最大发光效率为6.2cd/A;在15V驱动电压下,获得最大亮度为6 970cd/cm2,CIE坐标为(0.17,0.31)。这说明,BGIr1掺杂改善了器件的发光亮度和色纯度,提高了器件的发光效率。

【Abstract】 The six greenish-blue phosphorescent organic light emitting devices(OLEDs)with different greenish-blue light-emitting iridium(BGIr1)doped contents using 1,3-bis(9H-carbazal-9-yl)benzene(mCP)as host emitting material,BGIr1as doped material were fabricated by OLED-V organic multifunctional coating machine.The influence of BGIr1doping content on the luminous performance of greenish-blue phosphorescent OLEDs is investigated by Keithley Source 2400,the current-voltage instrument and PR-655photometer.The structure of as-prepared OLED is ITO/MoO3(20nm)/NPB(40nm)/mCP:BGIr1(x%,30nm)/BCP(10nm)/Alq3(20nm)/LiF/Al(100nm),where x%is the doping content of BGIr1in emitting layer.The experimental results show that the luminous performance of the OLED doped with 18% BGIr1is the best.The two main emitting peaks are gained at 488nm and 512nm,respectively for the OLED doped with 18%BGIr1,and the optical luminous efficiency of 6.2cd/A is obtained at current density of 26.5mA/cm2.The optical luminance of 6 790cd/A is acquired at driving voltage of 15V,and the CIE coordinates are(0.17,0.31).The results demonstrate that the luminous efficiency,luminance and purity of the greenish-blue OLED doped with BGIr1are all improved.

【基金】 陕西省教育厅产业化(06JC23);陕西科技大学研究生创新基金资助项目
  • 【文献出处】 光电子.激光 ,Journal of Optoelectronics.Laser , 编辑部邮箱 ,2014年01期
  • 【分类号】TN383.1
  • 【被引频次】13
  • 【下载频次】2220
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