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6061铝合金上硅烷膜的制备与性能

Preparation and Properties of Silane Film on 6061 Aluminium Alloy Surface

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【作者】 雷越汤宏伟张圣麟

【Author】 LEI Yue;TANG Hong-Wei;ZHANG Sheng-lin;School of Chemistry and Chemical Engineering,Henan Normal University;

【机构】 河南师范大学化学化工学院

【摘要】 采用浸涂技术,在6061铝合金表面制备了γ-氨丙基三甲氧基硅烷膜。采用电化学方法和SEM研究了其在3.5%NaCl溶液中的耐蚀性及形貌。结果表明,当硅烷浓度为3%(体积分数),溶液pH为12,室温下水解时间72h形成的硅烷溶液具有较好的稳定性;铝合金试样在硅烷溶液中浸涂3min,固化温度180℃,固化时间120min,其表面形成的硅烷膜的耐蚀性最佳,表现为腐蚀电流密度降低和腐蚀电位的升高。

【Abstract】 Theγ-aminopropyltriethoxysilane film was deposited on 6061aluminium alloy surface.The corrosion resistance of the silane film was investigated in 3.5% NaCl solution,using Tafel polarization curves.The results showed that silane solution was stable when the silane concentration was 3%,pH value was 12and time of hydrolysis was 72hat room temperature.When aluminum alloy specimen in silane solution was treated by dip-coating 3min, curing temperature 180℃and curing time 120min.the obtained silane films on 6061aluminium alloy surface had the best corrosion resistance,the corrosion current density reduced and corrosion potential rose.

  • 【文献出处】 腐蚀与防护 ,Corrosion & Protection , 编辑部邮箱 ,2014年01期
  • 【分类号】TG174.4
  • 【被引频次】18
  • 【下载频次】178
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