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采用TiH2预处理的SiC陶瓷柱阵列增强/高铬铸铁复合材料界面与耐磨性能(英文)

Interface and Wear Resistance of SiC Ceramic Column Grid Array Reinforced High-Chromium Cast Iron Composite Pretreated with TiH2

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【作者】 刘桂武张相召王倩叶志国史忠旗乔冠军

【Author】 Liu Guiwu;Zhang Xiangzhao;Wang Qian;Ye Zhiguo;Shi Zhongqi;Qiao Guanjun;Jiangsu University;State Key Laboratory for Mechanical Behavior of Materials,Xi’an Jiaotong University;Nanchang Hangkong University;

【机构】 江苏大学西安交通大学金属材料强度国家重点实验室南昌航空大学

【摘要】 利用TiH2粉末膏剂涂覆和在真空下1000或1400℃保温20 min的预处理工艺对反应烧结SiC陶瓷柱进行了表面预处理,再将预处理好的SiC陶瓷柱固定在石墨板上,随后采用金属浇铸工艺制备了一种具有高度陶瓷增强体宏观均匀性、可靠性和可设计性的SiC陶瓷柱阵列增强高铬铸铁复合材料。陶瓷涂层和复合材料界面分析表明:1400℃为较优的SiC表面预处理温度,预处理后SiC表面形成一层可靠的金属性复合层。该复合层在高温浇注过程中不会被溶解,可有效抑制高铬铸铁与SiC陶瓷的界面反应,从而形成无脱层、优良的复合材料陶瓷/金属磨损界面。与该复合材料的金属基体相比,由于SiC陶瓷柱的有效添加,经表面处理后不同陶瓷含量的SiC/高铬铸铁复合材料的耐磨性能均显著提高。

【Abstract】 Reaction-bonded SiC ceramic columns were coated by titanium hydride(TiH2) powder paste firstly,and then pretreated in a vacuum at 1000 or 1400 oC for 20 min.After that,the pretreated SiC ceramic columns were fixed on a graphite plate.Subsequently,a kind of SiC ceramic column grid array reinforced high-chromium cast iron composites,with high macro-uniformity,reliability and designability of the ceramic reinforcements,were fabricated by metal casting.The microstructure analysis on the ceramic coating and the ceramic/metal interface of the SiC/iron composite reveals that a reliable metallic composite coating can be formed on the SiC surface after the pretreatment at 1400 oC which was proved to be a better pretreatment temperature.The as-formed coating would not be dissolved during the metal casting process,and the interfacial reactions between SiC and iron were also restrained effectively,resulting in an excellent ceramic/metal interface without delamination after wear testing.Moreover,the wear resistances of the SiC/iron composites with different SiC ceramic contents are improved markedly in comparison with that of the metal matrix due to the effective additions of SiC ceramic columns.

【基金】 The National High-Tech R&D Program of China(2012AA040209);the Key Grant Project of Chinese Ministry of Education(313046);the Program for New Century Excellent Talents in University(NCET–11–0425);the Post Doctorial Science Foundation of China
  • 【文献出处】 稀有金属材料与工程 ,Rare Metal Materials and Engineering , 编辑部邮箱 ,2014年10期
  • 【分类号】TB333
  • 【被引频次】7
  • 【下载频次】174
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