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掺杂SnO2对超级电池中炭电极的影响

Effects of carbon electrode doped with SnO2 in ultra-battery

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【作者】 龙璐施利勇邹献平朱健舒东方明学

【Author】 LONG Lu;SHI Li-yong;ZOU Xian-ping;ZHU Jian;SHU Dong;FANG Ming-xue;School of Chemistry and Environment,South China Normal University;Tianneng Battery Group;Base of Production,Education & Research on Energy Storage and Power Battery of Guangdong Higher Education Institutes;Key Laboratory of Energy Conversion and Energy Storage Materials;

【机构】 华南师范大学化学与环境学院天能电池集团有限公司广东高校储能与动力电池产学研结合示范基地广州市能源转化与储能材料重点实验室

【摘要】 本文使用钛片作为集流体制作了掺杂不同含量SnO2析氢抑制剂的炭电极,同时采用了循环伏安、线性扫描、恒流充放电、交流阻抗对其进行了电化学性能测试。实验结果表明,掺杂SnO2的炭电极对析氢具有明显的抑制作用,且比电容也得到了一定的提高;此外,掺杂SnO2的最佳含量为5%。

【Abstract】 In this paper,titanium plate was used as current collector added different percentage content of SnO2 to make carbon electrode,in which SnO2 was used as hydrogen evolution inhibition.In the meantime,these carbon electrodes were evaluated by cyclic voltammetry,linear sweep voltammetry,galvanostatic charge-discharge,and electrochemical impedance spectroscopy.The experimental results showed that carbon electrodes doped with SnO2 which was usually used as evolution inhibitor were signifi cantly inhibited and the ratio of the capacitance had also been improved to some extent; furthermore,the best adding proportion of SnO2 was 5 %.

【基金】 国家自然科学基金(21273085);广州市科技计划项目(2012J4300147);广东省教育部产学研结合项目(2010B090400552);广东省自然科学基金(S2011010003416)
  • 【分类号】TM912
  • 【被引频次】3
  • 【下载频次】110
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