Synthesis and crystal structure of bis (1,3-diisopropyl-4,5-dimethylimidazolium) hexatungstate

【摘要】 The title compound bis（1,3-diisopropyl-4,5-dimethylimidazolium） hexatungstate,[C₁1H₂1N₂]₂[W₆O₁9],was synthesized and characterized by single-crystal X-ray diffraction,IR and elemental analysis.It crystallizes in the monoclinic system,space group P2₁/n with a=1.112 84（14）,b=1.283 84（17）,c=1.293 28（17）nm,β=96.410（2）°,V=1.836 2（4）nm³,C22H42N4O19W6,Mr=1 769.70,Dc=3.201 g/cm3,F（000）=1 596,Z=2,μ（Mo Kα）=18.797 mm-1,the final R=0.031 3,wR=0.059 8for observed reflections（I>2σ（I））.更多还原

【Abstract】 The title compound bis（1,3-diisopropyl-4,5-dimethylimidazolium） hexatungstate,[C₁1H₂1N₂]₂[W₆O₁9],was synthesized and characterized by single-crystal X-ray diffraction,IR and elemental analysis.It crystallizes in the monoclinic system,space group P2₁/n with a=1.112 84（14）,b=1.283 84（17）,c=1.293 28（17）nm,β=96.410（2）°,V=1.836 2（4）nm³,C22H42N4O19W6,Mr=1 769.70,Dc=3.201 g/cm3,F（000）=1 596,Z=2,μ（Mo Kα）=18.797 mm-1,the final R=0.031 3,wR=0.059 8for observed reflections（I>2σ（I））.更多还原