【摘要】 Ullmann反应被广泛用于有机中间体的合成,包括C—C,C—O,C—S,C—N键的形成.近年的研究表明,微波能加速Ullmann反应,并能明显提高其反应产率.因此,微波在Ullmann反应中的应用日益受到人们的重视.围绕C—C,C—O,C—S,C—N键的形成,对微波在反应中的应用进展进行了综述.更多还原

【Abstract】 The Ullmann reaction has been extensively applied in the synthesis of organic intermediates, especially in the formation of carbon-carbon bond, carbon-oxygen bond, carbon-sulfur bond and carbon-nitrogen bond. It has been demonstrated that microwave irradiation can obviously accelerate the Ullmann reaction and improve the yields, so the application of microwave in the Ullmann reaction has caught increasing attention in recent years. The application of microwave in the Ullmann reaction and the progresses in the formation of carbon-carbon bond, carbon-oxygen bond, carbon-sulfur bond and carbon-nitrogen bond are reviewed in this paper.更多还原