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硫酸镁对硼酸介稳区性质的影响

The Effect of Magnesium Sulfate on the Metastable Zone Property of Boric Acid

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【作者】 李丽丽董亚萍彭姣玉李武孟庆芬

【Author】 LI Li-li1,2,DONG Ya-ping1,PENG Jiao-yu1,LI Wu,MENG Qing-fen1(1.Qinghai Institute of Salt Lakes,Chinese Academy of Sciences,Xining,810008,China; 2.University of Chinese Academy of Sciences,Beijing,100049,China)

【机构】 中国科学院青海盐湖研究所中国科学院大学

【摘要】 通过浊度法测定10℃~45℃范围内MgSO4-H3BO3-H2O体系中硼酸的溶解度及介稳区宽度,得到硼酸的成核方程,并计算其表观成核级数。实验结果表明,硫酸镁的存在降低了硼酸的溶解度;随着硫酸镁浓度的升高,硼酸的介稳区宽度先变宽后变窄;硫酸镁的加入使硼酸的表观成核级数增加。

【Abstract】 The solubility and metastable zone width of boric acid in MgSO4-H3BO3-H2O system were determined in the temperature range from 10 ℃ to 45 ℃ by turbidity method,the formulas of nucleation were obtained and the apparent nucleation orders of boric acid were calculated.The results showed that,the presence of magnesium sulfate decreases the solubility of boric acid;The metastable zone width of boric acid first becomes wider and then narrower with increasing concentrations of magnesium sulfate;the addition of magnesium sulfate increases the apparent nucleation orders of boric acid.

【关键词】 硼酸硫酸镁溶解度介稳区
【Key words】 Boric acidMagnesium sulfateSolubilityMetastable zone width
【基金】 国家自然科学基金(41273032);青海省科技厅项目(2009-G-202)
  • 【文献出处】 盐湖研究 ,Journal of Salt Lake Research , 编辑部邮箱 ,2013年01期
  • 【分类号】O645.5
  • 【被引频次】7
  • 【下载频次】185
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