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动态硫化丙烯酸酯橡胶/聚对苯二甲酸乙二醇酯热塑性弹性体补强体系的研究

Study on Reinforcing System of Acrylate Rubber/Polyethylene Terephthalate Thermoplastic Vulcanizates

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【作者】 于海宁韩吉彬段红云伍社毛张立群

【Author】 YU Hai-ning;HAN Ji-bin;DUAN Hong-yun;WU She-mao;ZHANG Li-qun;Beijing University of Chemical Technology;

【机构】 北京化工大学 北京市新型高分子材料制备与加工重点实验室

【摘要】 采用动态硫化法制备丙烯酸酯橡胶(ACM)/聚对苯二甲酸乙二醇酯(PET)热塑性硫化胶(TPV),并研究硅土、炭黑和白炭黑对TPV物理性能、流变性能和耐油性能的影响。结果表明:与硅土和炭黑相比,白炭黑对ACM/PET TPV的补强效果较好;白炭黑的填料网络结构使TPV的表观粘度明显增大;白炭黑的加入能够提高TPV的物理性能和耐油性能,当白炭黑用量为50份时,所制得的ACM/PET TPV综合性能最佳。

【Abstract】 The acrylate rubber(ACM)/polyethylene terephthalate(PET)thermoplastic vulcanizate(TPV)was prepared by dynamic vulcanization method,and the influence of different reinforcing agents(siliceous earth,carbon black and silica)on the physical properties,rheological property and oil resistance of ACM/PET TPV was investigated.The results showed that,compared with siliceous earth and carbon black,silica was more effective in the reinforcement of ACM/PET TPV.By adding silica,the apparent viscosity of ACM/PET TPV increased,and the physical properties and oil resistance of ACM/PET TPV were significantly improved.When the addition level of silica was 50phr,the comprehensive properties of ACM/PET TPV was the best.

【基金】 国家重点基础研究发展计划项目(2011CB606003)
  • 【文献出处】 橡胶工业 ,China Rubber Industry , 编辑部邮箱 ,2013年09期
  • 【分类号】TQ330.15
  • 【被引频次】4
  • 【下载频次】207
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