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Synthesis and Improved Acetone Sensing Properties of Porous α-Fe2O3 Nanowires

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【作者】 刘丽迟霄王国光刘唱白陕皓张晓波王连元关宏宇

【Author】 LIU Li;CHI Xiao;WANG Guo-Guang;LIU Chang-Bai;SHAN Hao;ZHANG Xiao-Bo;WANG Lian-Yuan;GUAN Hong-Yu;State Key Laboratory of Superhard Materials,College of Physics,Jilin University;College of Electronic Science and Engineering,Jilin University;College of Chemistry,Northeast Normal University;

【机构】 State Key Laboratory of Superhard Materials,College of Physics,Jilin UniversityCollege of Electronic Science and Engineering,Jilin UniversityCollege of Chemistry,Northeast Normal University

【摘要】 Porous α-Fe2O3 nanowires are synthesized by a simple wet chemical method with a precursor of peroxyacetyl nitrate(PAN),and α-Fe2O3 nanoparticles are also synthesized in the same way except for the addition of PAN.Gas sensors are fabricated by coating the samples on ceramic tubes with Au signal electrodes and Ni-Cr heaters.A sensing investigation reveals that the porous α-Fe2O3 nanowires have a higher sensitivity compared to α-Fe2O3 nanoparticles at 260℃.The corresponding sensor response(Ra/Rg) is 18.2 at the maximum to 100ppm acetone,and the response and recovery times are about 8 and 12 s,respectively.The porous and one-dimensional nanostructures of the porous α-Fe2O3 nanowires benefit for the gas-absorption and electrical-signal-transfer,and thus improve the sensor sensitivity consequentially.

【Abstract】 Porous α-Fe2O3 nanowires are synthesized by a simple wet chemical method with a precursor of peroxyacetyl nitrate(PAN),and α-Fe2O3 nanoparticles are also synthesized in the same way except for the addition of PAN.Gas sensors are fabricated by coating the samples on ceramic tubes with Au signal electrodes and Ni-Cr heaters.A sensing investigation reveals that the porous α-Fe2O3 nanowires have a higher sensitivity compared to α-Fe2O3 nanoparticles at 260℃.The corresponding sensor response(Ra/Rg) is 18.2 at the maximum to 100ppm acetone,and the response and recovery times are about 8 and 12 s,respectively.The porous and one-dimensional nanostructures of the porous α-Fe2O3 nanowires benefit for the gas-absorption and electrical-signal-transfer,and thus improve the sensor sensitivity consequentially.

【基金】 Supported by the Jilin Environment Office(No 2009-22);Jilin Provincial Science and Technology Department(No 20100344);the National Innovation Experiment Program for University Students(No 2010C65188)
  • 【文献出处】 Chinese Physics Letters ,中国物理快报(英文版) , 编辑部邮箱 ,2013年02期
  • 【分类号】TP212
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