Crystallization Kinetics and Magnetic Properties of Fe_73.5Si_13.5B₉Cu₁Nb₁V₂ Nanocrystalline Powder Cores

【摘要】 Amorphous ribbons of the alloy Fe73.5Si13.5B9Cu1Nb1V2 were prepared by the standard single copper wheel melt spinning technique in the air atmosphere.The crystallization kinetics of amorphous ribbons was analyzed by non-isothermal differential scanning calorimetry(DSC) measurements.The crystallization activation energies of amorphous ribbons calculated by using Kissinger model were 364 and 337 kJ/mol for the first and the second crystallization,respectively.The Avrami exponent n was calculated from the Johnson- Mehl-Avrami(JMA) equation.The value of the Avrami exponent showed that the crystallization mechanism in the non-isothermal primary crystallization of amorphous ribbons was all shapes growing from small dimensions controlled by diffusion at decreasing nucleation rate.The variation of soft magnetic properties of nanocrystalline Fe73.5Si13.5B9Cu1Nb1V2 alloy powder cores as a function of milling times has been investigated.It is found that the effective permeability of the cores shows high frequency stability and decreases with the increase of milling times.The quality factor increases with increasing frequency in lower frequency range,and reaches a maximum at the frequency of 80 kHz then decreases gradually with increasing frequency.更多还原

【Abstract】 Amorphous ribbons of the alloy Fe73.5Si13.5B9Cu1Nb1V2 were prepared by the standard single copper wheel melt spinning technique in the air atmosphere.The crystallization kinetics of amorphous ribbons was analyzed by non-isothermal differential scanning calorimetry(DSC) measurements.The crystallization activation energies of amorphous ribbons calculated by using Kissinger model were 364 and 337 kJ/mol for the first and the second crystallization,respectively.The Avrami exponent n was calculated from the Johnson– Mehl–Avrami(JMA) equation.The value of the Avrami exponent showed that the crystallization mechanism in the non-isothermal primary crystallization of amorphous ribbons was all shapes growing from small dimensions controlled by diffusion at decreasing nucleation rate.The variation of soft magnetic properties of nanocrystalline Fe73.5Si13.5B9Cu1Nb1V2 alloy powder cores as a function of milling times has been investigated.It is found that the effective permeability of the cores shows high frequency stability and decreases with the increase of milling times.The quality factor increases with increasing frequency in lower frequency range,and reaches a maximum at the frequency of 80 kHz then decreases gradually with increasing frequency.更多还原