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溶胶-凝胶法制备新型锂离子负极材料MnV2O6

Preparation of MnV2O6 via sol-gel method for lithium ion battery

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【作者】 张利玉严铁军陈珊刘芳芳汪振忠郭光辉

【Author】 ZHANG Li-yu;YAN Tie-jun;CHEN Shan;LIU Fang-fang;WANG Zheng-zhong;GUO Guang-hui;Hubei Coal Conversion and New Carbon Materials Key Laboratory,College of Chemical Engineering and Technology,Wu han university of Science and Technology;

【机构】 湖北省煤转化与新型炭材料重点实验室武汉科技大学化学工程与技术学院

【摘要】 偏钒酸锰MnV2O6具有特殊的钛铀矿结构,被认为是最有希望成为锂离子电池的负极材料之一。采用溶胶-凝胶法制备出的MnV2O6,对其结构和形貌进行表征,结果表明所制得的样品结晶度高,无杂相,颗粒粒径较均匀。

【Abstract】 Manganese metavanadate with special brannerite structure was proposed to be the most promising used for the anode of lithium ion batteries.MnV2O6 was prepared by the sol-gel method,using citric acid as a chelating agent,V2O5 and Mn(CH3COO)2·4H2O as starting materials.The sample was characterized by X-ray diffraction(XRD),scanning electronic microscopy(SEM).The results showed that the MnV2O6 anode material has high crystallinity,no impurity phase,and well-distributed size of the particles.

  • 【分类号】TM912
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