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乙醇裂解协同制备氢气和碳纳米管

The decomposition of ethanol to produce hydrogen and multi-wall carbon nanotubes

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【作者】 刁金香王惠

【Author】 DIAO Jin-xiang;WANG Hui;College of Aeronautical Material Engineering,Xi’an Aeronautical Polytechnic Institute;Key Laboratory of Synthetic and Natural Functional Molecule Chemistry (Ministry of Education) ,College of Chemistry & Materials Science,Northwest University;

【机构】 西安航空职业技术学院航空材料工程学院西北大学化学与材料科学学院合成与天然功能分子化学教育部重点实验室

【摘要】 以乙醇为碳源,采用浸渍法制备的担载量为Fe(5%)/C催化剂,利用化学气相沉积法协同制备碳纳米管和氢气,分析了裂解温度(500~800℃)对于产生氢气产率和碳纳米管品质的影响。对于Fe(5%)/C催化裂解乙醇,最佳的反应温度为600℃,碳管的品质较好,氢气的产率最高为75%,生成的碳管为多壁碳纳米管。

【Abstract】 Ethanol as carbon source,the effects of reaction temperature on the yield of hydrogen and the quality of carbon nanotubes(CNTs) over the Fe(5%) / C from the decomposition were investigated systematically.Ethanol decomposition was studied over Fe(5%) / C to produce hydrogen and carbon nanotubes by chemical vapor deposition at the temperature of 500 ~ 800 ℃.The optimal reaction temperature was 600 ℃ for hydrogen and the growth of MWCNT from ethanol decomposition over the Fe(5%) / C,H 2 yield was 75%,the produced carbon nanotubes was multi-walled carbon nanotubes(MWCNTs)(being of relatively higher and low defect).

【基金】 国家自然科学基金国际合作研究项目(21061130551);教育部博士点基金(20096101110002)
  • 【文献出处】 应用化工 ,Applied Chemical Industry , 编辑部邮箱 ,2013年09期
  • 【分类号】TQ116.2;TQ127.11
  • 【被引频次】1
  • 【下载频次】141
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