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硫醇甲基锡合成方法研究
Study on the Synthesis Methods of Methylitin Mercaptide
【摘要】 通过在一甲基三氯化锡和二甲基二氯化锡混合物加入氢氧化钠,利用生成的产物与水的相容性不同达到分离目的。分别向分离中的一甲基三氯化锡和二甲基二氯化锡加入巯基乙酸异辛酯,合成相应的纯度较高的一甲基锡三硫代乙酸异辛酯和二甲基锡二硫代乙酸异辛酯单体,可以将二者按不同比例混合得到不同的产品,满足各种不同的加工需求。
【Abstract】 In this paper,products separation is achieved by adding NaOH to mixture of methyl tin chloride and dimethyl tin dichloride and through the difference of their compatibilities with water. Then respectively adds isooctyl mercaptoacetate in these products to synthetize higher purity monomers like methyltin tris(isooctyl thioacetate) and dimethyltin bis(2 isooctyl thioacetate) ,which can be mixed in different proportion to prepare different products and to satisfy different processing reqirements.
【关键词】 硫醇甲基锡;
合成;
一甲基三硫代乙酸异辛酯;
二甲基二硫代乙酸异辛酯;
【Key words】 Methyltin mercaptide; methyl tris (thioisooctyl acetate); dimethyl di (thioisooctyl acetate; synthesis);
【Key words】 Methyltin mercaptide; methyl tris (thioisooctyl acetate); dimethyl di (thioisooctyl acetate; synthesis);
- 【文献出处】 塑料助剂 ,Plastics Additives , 编辑部邮箱 ,2013年04期
- 【分类号】TQ314.245
- 【被引频次】3
- 【下载频次】163