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连续流反应器TiO2/AC光催化处理阿奇霉素废水

Photocatalytic Treatment of Azithromycin Wastewater in a Continuous Flow Reactor with TiO2/AC as Catalyst

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【作者】 罗晓赵彦尚会建洪刚周艳丽杨丽洁郑学明宋曰超

【Author】 LUO Xiao1,ZHAO Yan2,SHANG Hui-jian2,HONG Gang3,ZHOU Yan-li2,YANG Li-jie3,ZHENG Xue-ming2*,SONG Yue-chao1(1.College of Environmental Science and Engineering,Hebei University of Science and Technology,Shijiazhuang 050080,Hebei,China;2.College of Chemical & Pharmaceutical Engineering,Hebei University of Science and Technology,Shijiazhuang 050018,Hebei,China;3.Shijiazhuang Environmental Monitoring Center,Shijiazhuang 050011,Hebei,China)

【机构】 河北科技大学环境科学与工程学院河北科技大学化学与制药工程学院石家庄市环境监测中心

【摘要】 用溶胶凝胶法将TiO2负载于颗粒活性炭(AC)上,500℃焙烧得到TiO2/AC催化剂,用比表面积测定仪(BET)、扫描电镜(SEM)和XRD表征其结构。在连续流反应器中以紫外灯为光源,光催化氧化处理阿奇霉素废水,并优化工艺参数。结果表明,在TiO2/AC中w(TiO2)=1.24%、pH=4,水力停留时间90 min条件下,阿奇霉素去除率≥94.1%,反应器连续运行240 h催化剂活性无明显下降。

【Abstract】 Activated carbon was loaded with TiO2 by sol-gel method,and then calcinated at 500 ℃ under the protection of nitrogen.TiO2/AC was characterized by means of BET,scanning electron microscope(SEM) and XRD.Photocatalytic oxidation of azithromycin with TiO2/AC was conducted in a continuous flow reactor with ultraviolet lamp as illuminant.The results show that the removal rate of azithromycin was not less than 94.1% under the conditions of w(TiO2) of TiO2/AC=1.24%,pH=4 and hydraulic retention time 90 min.After 240 hours′ continuous running,the catalytic activity of TiO2/AC exhibited no obvious decline.

【基金】 河北省高校重点学科建设项目资助~~
  • 【分类号】X787
  • 【被引频次】5
  • 【下载频次】296
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