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连续流反应器TiO2/AC光催化处理阿奇霉素废水
Photocatalytic Treatment of Azithromycin Wastewater in a Continuous Flow Reactor with TiO2/AC as Catalyst
【摘要】 用溶胶凝胶法将TiO2负载于颗粒活性炭(AC)上,500℃焙烧得到TiO2/AC催化剂,用比表面积测定仪(BET)、扫描电镜(SEM)和XRD表征其结构。在连续流反应器中以紫外灯为光源,光催化氧化处理阿奇霉素废水,并优化工艺参数。结果表明,在TiO2/AC中w(TiO2)=1.24%、pH=4,水力停留时间90 min条件下,阿奇霉素去除率≥94.1%,反应器连续运行240 h催化剂活性无明显下降。
【Abstract】 Activated carbon was loaded with TiO2 by sol-gel method,and then calcinated at 500 ℃ under the protection of nitrogen.TiO2/AC was characterized by means of BET,scanning electron microscope(SEM) and XRD.Photocatalytic oxidation of azithromycin with TiO2/AC was conducted in a continuous flow reactor with ultraviolet lamp as illuminant.The results show that the removal rate of azithromycin was not less than 94.1% under the conditions of w(TiO2) of TiO2/AC=1.24%,pH=4 and hydraulic retention time 90 min.After 240 hours′ continuous running,the catalytic activity of TiO2/AC exhibited no obvious decline.
【Key words】 TiO2; activated carbon; photo catalytic oxidation; azithromycin; water treatment technology and environmental protection;
- 【文献出处】 精细化工 ,Fine Chemicals , 编辑部邮箱 ,2013年03期
- 【分类号】X787
- 【被引频次】5
- 【下载频次】296