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Al涂层对γ-TiAl合金高温抗氧化能力的影响
Effect of Al coatings on high-temperature oxidation resistance of γ-TiAl alloy
【摘要】 研究了多弧离子镀铝对γ-TiAl合金850℃、950℃恒温氧化性能的影响,同时分析讨论了镀铝层的氧化机制。结果表明:多弧离子镀铝后,形成的纯铝涂层均匀致密,无裂纹、孔洞,与基体结合良好。静态空气中,850℃氧化100 h后,形成了连续致密的A12O3膜层及扩散层TiAl3相;950℃氧化100 h后,表面氧化膜由A12O3及少量的TiO2组成,膜层中TiAl2为主要成膜相。多弧离子镀铝有效地提高了γ-TiAl合金高温抗氧化性能。
【Abstract】 Isothermal oxidation behavior of γ-TiAl alloy,which was aluminized at 850 ℃ and 950 ℃ by multi-arc ion plating(MAIP),were investigated.The oxidation mechanism of Al coatings was also discussed.The results show that the multi-arc ion plating aluminum films are compact and consist of Al,no cracks,holes,but with good binding capacity.They turn to a continuous and dense layer of A12O3 and the diffusion layer TiAl3 after oxidation at 850 ℃ in air for 100 h;after high temperature oxidation at 950 ℃ in static air for 100 h,the surface oxidation film is formed of A12O3 and a little of TiO2,and TiAl2 is mostly phase in the film.The high temperature oxidation resistance of γ-TiAl alloy is improved obviously after multi-arc ion plating aluminum.
【Key words】 TiAl-based alloy; MAIP; high temperature oxidation; aluminum castings;
- 【文献出处】 材料热处理学报 ,Transactions of Materials and Heat Treatment , 编辑部邮箱 ,2013年S1期
- 【分类号】TG174.44
- 【被引频次】6
- 【下载频次】226