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Phase Diagram, Growth and Optical Property of the LaBWO6 Crystal

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【作者】 孙传祥林州斌张莉珍黄溢声王国富

【Author】 SUN Chuan-Xiang a, b LIN Zhou-Bin a ZHANG Li-Zhen a HUANG Yi-Sheng a WANG Guo-Fu a a (Key Laboratory of Optoelectronics Material Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China) b (University of the Chinese Academy of Sciences, Beijing 100039, China)

【机构】 Key Laboratory of Optoelectronics Material Chemistry and Physics,Fujian Institute of Research on the Structure of Matter,Chinese Academy of SciencesUniversity of the Chinese Academy of Sciences

【摘要】 The phase diagram, growth and optical property of LaBWO6 crystal are reported. LaBWO6 crystal melts congruently at 1078 ℃. Based on the pseudo-ternary phase diagram of LaBWO6 (Li2WO4 /LiF) B2O3 , the LaBWO6 crystals have been firstly grown by the flux method. LaBWO6 crystal crystallizes in the orthorhombic system, space group P222 with a = 4.1, b = 10.31 and c = 21.71 . LaBWO6 crystal exhibits high transparency in a range from 327 to 1100 nm. The absorption edge of the crystal in the UV range is at 293 nm. The SHG efficient of LaBWO6 crystal is 0.3 times as large as that of the KDP crystal.

【Abstract】 The phase diagram, growth and optical property of LaBWO6 crystal are reported. LaBWO6 crystal melts congruently at 1078 ℃. Based on the pseudo-ternary phase diagram of LaBWO6 (Li2WO4 /LiF) B2O3 , the LaBWO6 crystals have been firstly grown by the flux method. LaBWO6 crystal crystallizes in the orthorhombic system, space group P222 with a = 4.1, b = 10.31 and c = 21.71 . LaBWO6 crystal exhibits high transparency in a range from 327 to 1100 nm. The absorption edge of the crystal in the UV range is at 293 nm. The SHG efficient of LaBWO6 crystal is 0.3 times as large as that of the KDP crystal.

【基金】 Supported by the NNSFC (No.61275177);the NSF of Fujian Province (No.2012I0011)
  • 【文献出处】 结构化学 ,Chinese Journal of Structural Chemistry , 编辑部邮箱 ,2013年07期
  • 【分类号】O611.4
  • 【被引频次】2
  • 【下载频次】33
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