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Fluorescence Quantum Efficiency Enhancement in CaWO4:Eu3+,Na+ Nanocrystals by Tridoping with F- Ions

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【作者】 张思念黄建华陈雨金龚兴红林炎富罗遵度黄艺东

【Author】 ZHANG Si-Niana, b HUANG Jian-Huaa CHEN Yu-Jina GONG Xing-Honga LIN Yan-Fua LUO Zun-Dua HUANG Yi-Donga② a (Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China) b (Graduate University of Chinese Academy of Sciences, Beijing 100039, China)

【机构】 Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of SciencesGraduate University of Chinese Academy of Sciences

【摘要】 We demonstrated that tridoping with F- ions is an effective way to improve the fluorescence quantum efficiency of CaWO4:Eu3+,Na+ nanocrystals. F--tridoped samples with different F- concentrations were synthesized by a hydrothermal process. The fluorescence spectra and decay curves were measured at room temperature. The fluorescence intensity of F--tridoped samples is about 3 times that for the non F--doped sample. The fluorescence quantum efficiency can be enhanced by 21% when the atomic ratio of F to W was 0.7.

【Abstract】 We demonstrated that tridoping with F- ions is an effective way to improve the fluorescence quantum efficiency of CaWO4:Eu3+,Na+ nanocrystals. F--tridoped samples with different F- concentrations were synthesized by a hydrothermal process. The fluorescence spectra and decay curves were measured at room temperature. The fluorescence intensity of F--tridoped samples is about 3 times that for the non F--doped sample. The fluorescence quantum efficiency can be enhanced by 21% when the atomic ratio of F to W was 0.7.

【基金】 Supported by the National Natural Science Foundation of China(No.51002152);the Natural Science Foundation of Fujian Province(No.2010J05125)
  • 【文献出处】 结构化学 ,Chinese Journal of Structural Chemistry , 编辑部邮箱 ,2013年01期
  • 【分类号】O614.3;TB383.1
  • 【被引频次】5
  • 【下载频次】76
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