【摘要】 亚铜[Cu(Ⅰ)]配合物因其低廉的价格、多样化的结构和独特的光物理性质一直备受关注.本文综述了常见磷光Cu(Ⅰ)配合物[Cu(NN)2]+、[Cu(NN)(PP)]+和(CuX)mLn(其中NN表示双齿二胺配体,PP表示二膦配体,X表示卤素,L表示含N或P配体)的光致发光与电致发光研究,揭示配合物结构与光学性质的关系,探讨近年来Cu(I)配合物在有机发光二极管(OLED)领域的应用研究新进展.更多还原

【Abstract】 Copper(Ⅰ) complexes have attracted considerable interest because of their rich photophysical properties and potential applications as inexpensive, abundant materials in organic light-emitting diode (OLED). Herein we review photoluminescence and electroluminescence study on several common copper(Ⅰ) complexes [Cu(NN)2] + , [Cu(NN)(PP)] + and (CuX)mLn (where NN indicates a chelating bisimine ligand, typically a substituted 1,10- phenanthroline; PP denotes a bisphosphine ligand; X means halide, such as I, Br, Cl and L equals a ligand that contains N or P coordination site). The relationship between structure and photoluminescence properties of copper(I) complexes and recent progress on copper(I) complexes based OLEDs are discussed.更多还原