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Chelex 100和Chilete P树脂分离水中Sr2+离子的研究
Study on separation of Sr2+ by Chelex 100 and Chilete Presin
【摘要】 通过对Chelex 100和Chilete P两种螯合树脂对水中Sr2+离子的静态和动态分离研究,考察浓度、pH值、体积和流速等条件的影响,设计正交实验,摸索树脂动态吸附和洗脱的工艺路线。结果表明:Chelex 100比Chilete P具有更好的Sr2+离子吸附效果,静态分离回收率分别为71.48%和51.49%。Chelex 100树脂的动态分离工艺:浓度为250mg·mL-1、pH值为3的Sr2+离子溶液20mL,以流速为3ml.min-1通过层析柱吸附;8mol.L-1的HNO3溶液以流速为2ml.min-1进行Sr2+离子的洗脱;获得最终回收率为87.08%。
【Abstract】 The study on the application of chelating resin to separation of strontium metal ions was given.The adsorbing concentration,pH value,volume and velocity of flow of Chelex 100 and Chelite P resin from strontium solutions were studied in a batch reactor.Otherwise,orthogonal test was designed.The results show that adsorbing capacity of Chelex 100 resin was strong than Chelite P.the recovery of Sr2+were 71.48%and 51.49%for static state separation.The optimum conditions of Chelex 100 resin to separation of strontium ions are as following,absorption conditions:concentration 250mg·mL-1,pH 3,volume 20mL,velocity of flow 2ml.min-1;desorption conditions:HNO3 concentration 8mol·L-1,velocity of flow 2ml·min-1.Ultimately,the recovery of Sr2+was 87.08%.
【Key words】 chelating resin; Sr2+; adsorption; desorption; orthogonal test;
- 【文献出处】 化学研究与应用 ,Chemical Research and Application , 编辑部邮箱 ,2013年08期
- 【分类号】X703
- 【被引频次】1
- 【下载频次】98