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花状NaY(MoO42的合成和NaY(MoO42:Eu3+的光学性质(英文)

Synthesis of Flower-like NaY(MoO42 and Optical Property of NaY(MoO42:Eu3+

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【作者】 张悠金祝玮何红梅郑傲

【Author】 You-jin Zhang;Wei Zhu;Hong-mei He;Ao Zheng;Department of Chemistry,University of Science and Technology of China;

【机构】 中国科学技术大学化学系

【摘要】 用微波辅助水热-煅烧法成功合成了花状NaY(MoO42颗粒,用XRD、XPS、FESEM进行了表征,提出了花状NaY(MoO42颗粒可能的形成机理.采用相同的方法合成了NaY(MoO4)2:Eu3+荧光体,该荧光材料在612 nm处有一个强的发射峰,可用作白色发光二极管的红色磷光剂.此外,微波辅助水热-煅烧法可能发展成为制备其他花状稀土钼酸盐的有效途径.

【Abstract】 Flower-like NaY(MoO42 particles were synthesized through a microwave-assisted hydrothermal process followed by a subsequent calcination process.The products were characterized by X-ray diffraction,X-ray photoelectron spectroscopy,field-emission scanning electron microscopy.The possible formation mechanism of the flower-like NaY(MoO42 precursor was proposed.The NaY(MoO42:Eu3+ phosphors were also prepared and their luminescence properties showed the NaY(MoO42:Eu3+ materials with the emission peak at 612 nm had potential application as a red phosphor for white light-emitting diodes.Furthermore,the microwave-assisted hydrothermal process followed by a subsequent calcination process could be extended to prepare the other lanthanide molybdates with the flower-like morphology.

【基金】 supported by the National Natural Science Foundation of China(No.20273066)
  • 【文献出处】 Chinese Journal of Chemical Physics ,化学物理学报(英文版) , 编辑部邮箱 ,2013年04期
  • 【分类号】O611.3
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