【摘要】 在80℃下合成了1个新的标题化合物,通过元素分析、红外和单晶X-射线进行了表征。标题化合物属于三斜晶系,P-1空间群,a=0.671 14(9)nm,b=1.165 88(14)nm,c=1.401 83(18)nm,α=96.410 0(10)°,β=94.825 0(10)°,γ=97.901(2)°,V=1.074 2(2)nm3,Z=2。配合物由1个VO2、两个2,2’-联吡啶分子和1个NH4HSO4构成,NH4HSO4分子通过氢键在a方向形成一维超分子链状结构,通过荧光光谱研究了该化合物的荧光性质。更多还原

【Abstract】 The new oxidovanadium complex ·NH4HSO4 was synthesized at 80 ℃ and characterized via elemental analysis,IR and single crystal X-ray diffraction.The complex belongs to triclinic system,space group P-1,a=0.671 14(9) nm,b=1.165 88(14) nm,c=1.401 83(18) nm,α=96.410 0(10)°,β=94.825 0(10)°,γ=97.901(2)°,V=1.074 2(2) nm3,Z=2.The title complex consists of one VO2,two 2,2′-bibyridine molecules and one NH4HSO4 molecule.The hydrogen bonds construct one-dimensional(1D) chains along the a axis.The fluorescence property is also investigated.更多还原