【摘要】 以3,5-二溴对羟基苯甲醛和1,10-邻菲啰啉-5,6-二酮反应生成(L)配体。以L为主配体,对苯二甲酸为辅配体采用混合溶剂热法合成了过渡金属有机化合物,[L.(1,4-bdc).Cd]n,对该配位聚合物进行了红外光谱分析,元素分析,X-射线单晶衍射分析,热失重分析。X-单晶衍射分析表明,配合物为三维网状超分子结构。更多还原

【Abstract】 Ligand L have been synthesized by 3,5-dibromo-4-hydroxybenzaldehyde reacted with 1,10-phenanthroline-5,6-dione.Under hydrothermal conditions,a new coordination polymer,[L·(1,4-bdc)·Cd]n has been synthesized and characterized by elemental analysis,X-ray single crystal diffraction,TG,IR.The molecular structure of the complex was determinated by X-ray single crystal diffraction analysis.This is a 3D supramolecular architecture.更多还原