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导电铝浆用无铅玻璃粉的制备及性能研究

Study on preparation and properites of Pb-free glass powder for Al paste

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【作者】 张剑宇谈发堂王维乔学亮陈建国

【Author】 Zhang Jianyu1 Tan Fatang1,2 Wang Wei1,2 Qiao Xueliang1,2 Chen Jianguo1,2(1.School of Materials Science and Engineering, Huazhong University of Science and Technology,Wuhan 430074; 2.State Key Laboratory of Material Processing and Die & Mould Technology,Wuhan 430074)

【机构】 华中科技大学材料科学与工程学院华中科技大学材料成形与模具技术国家重点实验室

【摘要】 以Bi2O3、B2O3和ZnO为主要原料,制备了一种导电铝浆用无铅玻璃粉。利用XRD、DTA和SEM对所得玻璃粉进行了表征。结果表明,玻璃粉结构主要为非晶态,软化点在500℃左右,粒径小于5μm。以此玻璃粉为原料制备了一系列玻璃粉含量不同的导电铝浆,并将其印刷到太阳能电池片上,检测了太阳能电池片的性能。结果表明:玻璃粉含量为1%时,电池片铝膜电阻率最小;玻璃粉含量减少时,电池片耐水煮性能有所提升。

【Abstract】 A kind of Bi2O3-B2O3-ZnO Pb-free glass frits for Al paste was prepared,using Bi2O3,B2O3 and ZnO as main starting material.The as-prepared glass powder was characterized by X-ray diffraction(XRD),differential thermal analysis(DTA)and scanning electron microscope(SEM).Results showed that the glass powder was amorphous in majority,the softening point was about 500℃ and the mean grain size was less than 5μm.A series of solar cells were manufactured using Al paste by varying the content of glass powder in the Al paste,and their performance were tested.The results showed that when the content of glass powder in Al paste was 1%,the aluminum coating resistivity was lowest,and the boiling water resistance was improved with the decrease of the content of glass powder in Al paste.

【基金】 湖北省自然科学基金资助项目(2010CDB00501);广东省教育部产学研结合资助项目(2010B090400049)
  • 【文献出处】 化工新型材料 ,New Chemical Materials , 编辑部邮箱 ,2013年04期
  • 【分类号】TQ171.1;TM914.4
  • 【被引频次】12
  • 【下载频次】403
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