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铁(Ⅲ)模板-硫脲交联壳聚糖的合成及其对Fe(Ⅲ)和Fe(Ⅱ)吸附性能比较
Comparison of Adsorption Behavior of Fe(Ⅱ)and Fe(Ⅲ)Ions on Thiourea Cross-linked Chitosan with Fe(Ⅲ)as Template
【摘要】 合成了铁(Ⅲ)模板-硫脲交联壳聚糖,研究了F e(Ⅲ)和Fe(Ⅱ)在模板交联壳聚糖上的吸附行为。考察了pH值、接触时间等因素对吸附的影响,结果表明,适宜的pH值为5.0,吸附平衡时间为60min。研究了吸附热力学和吸附动力学,结果表明,吸附符合L angmuir模型和准二级动力学模型。
【Abstract】 A new type of thiourea cross-linked chitosan with Fe(Ⅲ) as template (TCCTS template) was synthesized.The adsorption of Fe(Ⅱ) and Fe(Ⅲ) on TCCTS template was studied.The effect factors such as pH,contact time on adsorption were considered.The results showed that the optimum pH value for adsorption was pH=5.0 and the adsorption equilibrium time was about 60 min.The adsorption isotherms and kinetics were investigated,equilibrium data agreed very well with the Langmuir model and the Pseudo second-order model could describe adsorption process better than Pseudo first-order model.
【Key words】 Iron; Thiourea; Cross-linked Chitosan; Template; Adsorption;
- 【文献出处】 光谱实验室 ,Chinese Journal of Spectroscopy Laboratory , 编辑部邮箱 ,2013年06期
- 【分类号】O647.3
- 【下载频次】118