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Co(Ⅱ)8-羟基喹啉配合物固载到蒙脱土催化剂的合成、表征及其催化性能的应用

Synthesis and Characterization of Immobilization of Cobalt(Ⅱ) 8-Quinolinol to Montmorillonite and Application of Its Catalytic Performance

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【作者】 吴淑杰郭晔唐斌阚秋斌

【Author】 WU Shu-Jie GUO Ye TANG Bin KAN Qiu-Bin (College of Chemistry,Jilin University,Changchun 130021,P.R.China)

【机构】 吉林大学化学学院

【摘要】 通过离子交换法成功地制备了Co(8-Q)2-MT,用XRD、SEM、FT-IR和UV-Vis等方法进行了表征,并研究了其在空气氧化苯乙烯反应中的催化性能及其回收利用率。结果表明,负载后的金属配合物保持了蒙脱土的结构,且在催化反应中具有很好的催化性能,对苯基环氧乙烷的选择性很高,回收利用率很高。

【Abstract】 Co(8-Q)2-MT was successfully synthesized by the ion exchange method,and was characterized by XRD,SEM,FTIR and UV-Vis methods.Furthermore,its catalytic performance in oxidation reaction of styrene in the air and recycling rate were investigated.The results showed that the loaded metal complex maintained the structure of montmorillonite,and had good catalytic performance in the catalytic reaction,as well as high selectivity of phenyl ethylene oxide,that also had a high recycling rate.

【关键词】 蒙脱土苯乙烯8-羟基喹啉空气
【Key words】 MontmorilloniteStyrene8-hydroxyquinolineAir
  • 【文献出处】 光谱实验室 ,Chinese Journal of Spectroscopy Laboratory , 编辑部邮箱 ,2013年01期
  • 【分类号】O643.36
  • 【被引频次】4
  • 【下载频次】115
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