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SYNTHESIS, PROPERTIES AND ELECTROPOLYMERIZATION OF STAR-SHAPED OLIGOTHIOPHENES WITH HEXAKIS(FLUOREN-2-YL)BENZENE AS CORE

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【作者】 Yang Zou； Yuan Liu； Jin-gui Qin；杨楚罗；

【Author】 Yang Zou, Yuan Liu, Jin-gui Qin and Chu-luo Yang** Department of Chemistry, Hubei Key Lab on Organic and Polymeric Opto-Electronic Materials, Wuhan University, Wuhan 430072, China

【机构】 Department of Chemistry, Hubei Key Lab on Organic and Polymeric Opto-Electronic Materials, Wuhan University；

【摘要】 Star-shaped oligothiophenes with hexakis(fluoren-2-yl)benzene (HFB) as cores were designed and synthesized. Grafting thiophene units to HFB results in a bond flattening of the core, and makes the molecules a flipping-twist shape. Their thermal, photophysical and electrochemical properties were studied. Highly cross-linked conjugated polymers can be produced by electropolymerization of T1-T3.更多还原

【Abstract】 Star-shaped oligothiophenes with hexakis(fluoren-2-yl)benzene (HFB) as cores were designed and synthesized. Grafting thiophene units to HFB results in a bond flattening of the core, and makes the molecules a flipping-twist shape. Their thermal, photophysical and electrochemical properties were studied. Highly cross-linked conjugated polymers can be produced by electropolymerization of T1-T3.更多还原

【关键词】 Star-shaped molecules； Hexakis(fluoren-2-yl)benzene； Oligothiophene； Electropolymerization.；
【Key words】 Star-shaped molecules； Hexakis(fluoren-2-yl)benzene； Oligothiophene； Electropolymerization.；

【基金】 supported by the National Science Fund for Distinguished Young Scholars of China(No. 51125013)

【文献出处】 Chinese Journal of Polymer Science ,高分子科学(英文版) , 编辑部邮箱 ,2013年06期

【分类号】O631.3
【被引频次】3
【下载频次】25

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