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层层组装构筑聚电解质/碳纳米管导电黏附膜

Fabrication of Electrically Conductive Adhesive Films of Polyelectrolyte/Carbon Nanotubes by Layer-by-Layer Assembly

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【作者】 张健夫李洋李志成王力风孙俊奇

【Author】 ZHANG Jian-Fu1,LI Yang1,LI Zhi-Cheng2,WANG Li-Feng2,SUN Jun-Qi1 (1.State Key Laboratory of Supramolecular Structure and Materials,College of Chemistry, 2.Alan G.MacDiarmid Institute,Jilin University,Changchun 130012,China)

【机构】 吉林大学化学学院超分子结构与材料国家重点实验室吉林大学化学学院麦克德尔米德实验室

【摘要】 首先将聚烯丙基胺盐酸盐与碳纳米管制成复合物(PAH-CNT),再通过层层组装技术构筑了聚丙烯酸和碳纳米管混合物(PAA-CNT)与PAH-CNT多层复合膜(PAH-CNT/PAA-CNT).PAH-CNT/PAA-CNT多层复合膜同时具有导电和黏附性能.在玻璃和ITO基片上沉积的PAH-CNT/PAA-CNT多层复合膜的最大拉伸剪切强度接近7 MPa,即1 cm2的黏附膜可以承受约70 kg的重物.碳纳米管的引入使PAH-CNT/PAA-CNT多层复合膜具有更好的导电性.

【Abstract】 Water-based highly adhesive films with satisfactory electrical conductivity were constructed by Layer-by-Layer(LbL) assembly technique.Poly(allylamine hydrochloride) and carbon nanotube(CNT) complexes(PAH-CNT) were assembled with a blend of poly(acrylic acid) and CNT(PAA-CNT) to produce PAH-CNT/PAA-CNT films.Strong adhesion as high as 7 MPa can be achieved when glass substrates deposited with LbL assembled PAH-CNT/PAA-CNT films are slightly pressed together,which means that the glued conductive adhesive films with an area of 1 cm2 can hold a weight of approximate 70 kg.The thin nature of the adhesive films and the incorporated carbon nanotubes endow the adhesive films with satisfactory electrical conductivity.

【基金】 国家自然科学基金(批准号:21225419,21221063)资助
  • 【文献出处】 高等学校化学学报 ,Chemical Journal of Chinese Universities , 编辑部邮箱 ,2013年07期
  • 【分类号】TB383.2
  • 【被引频次】2
  • 【下载频次】225
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