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Fe3O4/C的制备与电化学性能研究

Electrochemical Performance of Fe3O4/C Composites as Negative Material for Lithium-Ion Batteries

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【作者】 蔡俊杰姚姝李泽胜孟辉沈培康

【Author】 CAI Jun-jie,YAO Shu,LI Ze-sheng,MENG Hui,SHEN Pei-kang(State Key Laboratory of Optoelectronic Materials and Technologies,Guangdong Province Key Laboratory of Low-carbon Chemistry & Energy Conservation,School of Physics and Engineering,Sun Yat-sen University,Guangzhou 510275,China)

【机构】 中山大学光电材料与技术国家重点实验室广东省低碳化学与过程节能重点实验室物理科学与工程技术学院

【摘要】 应用共沉淀法并以原位聚合苯胺包覆Fe3O4作碳源制备Fe3O4/C的复合材料.XRD、SEM、TEM等测试显示,样品中Fe3O4纳米颗粒(40~80 nm)均匀分散在无定形碳的内部.在50 mA.g-1电流密度下,经过30次循环充放电测试,该材料的容量仍保持在1000 mAh.g-1左右.

【Abstract】 The Fe3O4/Carbon composites have been synthesized through coprecipitation pathway and by insitu aniline polymerization as a carbon source.Structural characterization and morphological study of the composites were investigated by using XRD,SEM and TEM techniques.The results showed that the nanosized Fe3O4 particles(40 ~ 80 nm) were encapsulated in the amorphous carbon.During the electrochemical tests,the Fe3O4/C composites exhibited high capaticity and excellent cycle ability,the retention of capaticity was about 1000 mAh·g-1 after 30 cycles of charge/discharge tests at 50 mA·g-1.

【基金】 国家自然科学基金(No.21073241,No.U1034003)资助
  • 【文献出处】 电化学 ,Journal of Electrochemistry , 编辑部邮箱 ,2013年01期
  • 【分类号】O646
  • 【被引频次】2
  • 【下载频次】341
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