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Fe3O4/C的制备与电化学性能研究
Electrochemical Performance of Fe3O4/C Composites as Negative Material for Lithium-Ion Batteries
【摘要】 应用共沉淀法并以原位聚合苯胺包覆Fe3O4作碳源制备Fe3O4/C的复合材料.XRD、SEM、TEM等测试显示,样品中Fe3O4纳米颗粒(40~80 nm)均匀分散在无定形碳的内部.在50 mA.g-1电流密度下,经过30次循环充放电测试,该材料的容量仍保持在1000 mAh.g-1左右.
【Abstract】 The Fe3O4/Carbon composites have been synthesized through coprecipitation pathway and by insitu aniline polymerization as a carbon source.Structural characterization and morphological study of the composites were investigated by using XRD,SEM and TEM techniques.The results showed that the nanosized Fe3O4 particles(40 ~ 80 nm) were encapsulated in the amorphous carbon.During the electrochemical tests,the Fe3O4/C composites exhibited high capaticity and excellent cycle ability,the retention of capaticity was about 1000 mAh·g-1 after 30 cycles of charge/discharge tests at 50 mA·g-1.
【Key words】 Fe3O4; negative materials; Li-ion batteries; amorphous carbon;
- 【文献出处】 电化学 ,Journal of Electrochemistry , 编辑部邮箱 ,2013年01期
- 【分类号】O646
- 【被引频次】2
- 【下载频次】341