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有机改性凹凸棒石吸附活性艳蓝KN-R的动力学研究

Kinetics of Adsorption of Reactive Brilliant Blue KN-R onto Organic Modified Attapulgite

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【作者】 张波彭书传王世亮张泽滨吴敏伟

【Author】 ZHANG Bo1,PENG Shuchuan2,WANG Shiliang1,ZHANG Zhebin3,WU Minwei1(1 Department of Chemical Engineering,Anhui Vocational and Technical College,Hefei 230051;2 School of Resources and Environmental Engineering,Hefei University of Technology,Hefei 230009; 3 Hefei Design Research Institute for Coal Industry,Hefei 230041)

【机构】 安徽职业技术学院化学工程系合肥工业大学资源与环境学院煤炭工业合肥设计研究院

【摘要】 通过静态吸附实验方法,研究了有机改性凹凸棒石吸附活性艳蓝KN-R的动力学行为。研究结果表明:准二级动力学模型能很好地描述活性艳蓝KN-R在有机改性凹凸棒石上的动力学行为,平衡吸附量q2随着KN-R初始浓度、振荡速度、温度的增加而增加。有机改性凹凸棒石吸附活性艳蓝KN-R主要是外表面吸附,吸附活化能为39.2kJ/mol,说明其为物理吸附、化学吸附综合作用的过程,其速率由化学过程与外扩散共同控制。

【Abstract】 By static adsorption experiments,the adsorption dynamics of organic modified attapulgite on reactive brilliant blue KN-R was studied.The results indicate that the adsorption of KN-R by organic modified attapulgite follows the pseudo-second order kinetic model.The amount of KN-R adsorbed at equilibrium(q2) increases with the increasing of initial mass concentration for KN-R,agitation speed and temperature.The results also show that KN-R is mainly adsorbed on the external surface of organic modified attapulgite,the adsorption activation energy is 39.2 kJ/mol.It means that the adsorption is a process combinated by physical and chemical adsorption,and the adsorption rate is controlled by not only chemical adsorption but also physical adsorption.

【基金】 安徽省高等学校优秀青年人才基金(2012SQRL246);国家自然科学基金(40672027)
  • 【分类号】X703
  • 【被引频次】3
  • 【下载频次】118
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