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铜缓蚀剂苯并三氮唑缓蚀机理的研究进展

Research Progress of Inhibition Mechanism of Benzotriazole as Corrosion Inhibitor of Copper

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【作者】 谢文州郦和生李志林杨玉

【Author】 XIE Wen-zhou1,2, LI He-sheng2, LI Zhi-lin1, YANG Yu2(1. College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, China; 2. Yanshan Branch, Sinopec BRICI, Beijing 102500, China).

【机构】 北京化工大学材料科学与工程学院中国石化北京北化院燕山分院

【摘要】 综述了数十年来苯并三氮唑(BTA)对铜缓蚀机理的研究成果,重点介绍了酸性、近中性、碱性及含氯介质中BTA所形成缓蚀膜的结构与组成、缓蚀作用类型:BTA通过在铜表面形成一层保护膜而抑制铜腐蚀,缓蚀膜的形成受到氧气、阳极极化、BTA浓度和pH值的影响,高BTA浓度及高pH值均有利于缓蚀膜的形成。

【Abstract】 A review was provided of the research progress of the inhibition mechanism of benzotriazole (BTA) as corrosion inhibitor for copper. The surface structure and composition as well as the corrosion inhibition type of protective films of BTA formed in acidic medium, nearly neutral medium and alkaline medium were highlighted. It was pointed out that BTA functioned to prevent Cu from corrosion by forming protective films on Cu surface. The formation of BTA protective films was affected by oxygen, anodic polarization, BTA concentration and pH value, while elevating BTA concentration and pH value favored the formation of the BTA protective films.

【关键词】 苯并三氮唑缓蚀剂缓蚀机理
【Key words】 benzotriazolecoppercorrosion inhibitorinhibition mechanism
  • 【文献出处】 材料保护 ,Materials Protection , 编辑部邮箱 ,2013年03期
  • 【分类号】TG174.42
  • 【被引频次】43
  • 【下载频次】1292
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