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正渗透—纳滤耦合处理苦咸水脱盐工艺

Technological Processes of Desalination Treatment for Brackish Water with Coupled Forward Osmosis-Nanofiltration System

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【作者】 时强张乾阮国岭初喜章

【Author】 Shi Qiang1,Zhang Qian2,Ruan Guoling2,Chu Xizhang2(1.Key Laboratory of Eco-Chemical Engineering,Ministry of Education,College of Chemistry and Molecular Engineering,Qingdao University of Science and Technology,Qingdao 266042,China; 2.The Institute of Seawater Desalination and Multipurpose Utilization,SOA(Tianjin),Tianjin 300192,China)

【机构】 青岛科技大学化学与分子工程学院生态化工教育部重点实验室国家海洋局天津海水淡化与综合利用研究所

【摘要】 以2 000 mg/L氯化钠模拟苦咸水,采用二价无机盐作为汲取液,研究了正渗透淡化苦咸水时的水通量;通过软件计算和试验研究了不同组成汲取液的纳滤性能,并且设计了二级纳滤系统用于汲取液的回收。结果表明:相同浓度时硫酸镁汲取液正渗透水通量最低,而氯化镁汲取液水通量最高;相反在纳滤过程中,硫酸镁汲取液性能最佳,氯化镁最差;稀释硫酸钠汲取液浓度为30 g/L时,二级纳滤过程可以将汲取液浓缩至初始浓度(60 g/L),并制得浓度低于500 mg/L的产水。

【Abstract】 Simulating 2 000 mg/L NaCl as brackish water,using divalent salt(Na2SO4,MgSO4,MgCl2 and their mixture solution) as draw solution,the water flux of forward osmosis(FO) for brackish water desalination was investigated.The nanofiltration(NF) performance for the recovery of draw solution was determined by software and experiment,and a dual NF process was designed for the recovery of diluted draw solution.Results show that the water flux of MgSO4 in FO process is lowest,and that of MgCl2 is highest.It is opposite in NF process that the NF performance of MgSO4 is best,and that of MgCl2 is worst.When the diluted draw solution of Na2SO4 is 30 g/L,it could be concentrated to the initial concentration(60 g/L) by a dual stage NF process,and the permeate TDS is lower than 500 mg/L.

【基金】 国家海洋公益性行业科研专项经费项目(No.200905017-1)
  • 【文献出处】 净水技术 ,Water Purification Technology , 编辑部邮箱 ,2012年05期
  • 【分类号】TQ028.8
  • 【被引频次】10
  • 【下载频次】1074
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